{"title":"高锰钢真空熔炼过程中的锰挥发行为研究","authors":"Jialiu Lei, Yongjun Fu, Li Xiong","doi":"10.24425/afe.2024.149277","DOIUrl":null,"url":null,"abstract":"As an alloying element in steel, manganese can considerably enhance the mechanical properties of structural steel. However, the Mn volatilisation loss in vacuum melting is severe because of the high saturated vapour pressure, resulting in an unstable Mn yield and Mn content fluctuation. Therefore, a systematic study of the volatilisation behaviour of Mn in vacuum melting is required to obtain a suitable Mn control process to achieve precise control of Mn composition, thereby providing a theoretical basis for industrial melting of high-Mn steel. In order to explore the Mn volatilization behavior, the volatilization thermodynamics and volatilisation rate of Mn, as well as the influence factors are discussed in this study. The results shows that Mn is extremely volatilised into the vapour phase under vacuum, the equilibrium partial pressure is closely related to Mn content and temperature. With an increase in the Mn content, a higher C content has a more obvious inhibitory effect on the equilibrium partial pressure of Mn. The maximum theoretical volatilisation rate of Mn shows a linear upward trend with an increase in Mn content. However, a higher C content has a more obvious effect on the reduction of the maximum theoretical volatilisation rate with the increase of Mn content. This study provides an improved understanding of Mn volatilisation behaviour as well as a theoretical foundation for consistent Mn yield control during the vacuum melting process of high-Mn steel.","PeriodicalId":8301,"journal":{"name":"Archives of Foundry Engineering","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on Mn Volatilization Behavior During Vacuum Melting of High-manganese Steel\",\"authors\":\"Jialiu Lei, Yongjun Fu, Li Xiong\",\"doi\":\"10.24425/afe.2024.149277\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"As an alloying element in steel, manganese can considerably enhance the mechanical properties of structural steel. However, the Mn volatilisation loss in vacuum melting is severe because of the high saturated vapour pressure, resulting in an unstable Mn yield and Mn content fluctuation. Therefore, a systematic study of the volatilisation behaviour of Mn in vacuum melting is required to obtain a suitable Mn control process to achieve precise control of Mn composition, thereby providing a theoretical basis for industrial melting of high-Mn steel. In order to explore the Mn volatilization behavior, the volatilization thermodynamics and volatilisation rate of Mn, as well as the influence factors are discussed in this study. The results shows that Mn is extremely volatilised into the vapour phase under vacuum, the equilibrium partial pressure is closely related to Mn content and temperature. With an increase in the Mn content, a higher C content has a more obvious inhibitory effect on the equilibrium partial pressure of Mn. The maximum theoretical volatilisation rate of Mn shows a linear upward trend with an increase in Mn content. However, a higher C content has a more obvious effect on the reduction of the maximum theoretical volatilisation rate with the increase of Mn content. This study provides an improved understanding of Mn volatilisation behaviour as well as a theoretical foundation for consistent Mn yield control during the vacuum melting process of high-Mn steel.\",\"PeriodicalId\":8301,\"journal\":{\"name\":\"Archives of Foundry Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-06-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Archives of Foundry Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.24425/afe.2024.149277\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Archives of Foundry Engineering","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.24425/afe.2024.149277","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
摘要
作为钢中的一种合金元素,锰能大大提高结构钢的机械性能。然而,由于饱和蒸汽压较高,真空熔炼中的锰挥发损失严重,导致锰收得率和锰含量波动不稳定。因此,需要对真空熔炼中锰的挥发行为进行系统研究,以获得合适的锰控制流程,实现对锰成分的精确控制,从而为高锰钢的工业熔炼提供理论依据。为了探索锰的挥发行为,本研究讨论了锰的挥发热力学和挥发速率以及影响因素。结果表明,锰在真空条件下极易挥发到气相中,其平衡分压与锰含量和温度密切相关。随着锰含量的增加,较高的 C 含量对锰的平衡分压有更明显的抑制作用。随着锰含量的增加,锰的最大理论挥发率呈线性上升趋势。然而,随着锰含量的增加,较高的 C 含量对最大理论挥发率的降低有更明显的影响。这项研究加深了对锰挥发行为的理解,并为在高锰钢真空熔炼过程中实现一致的锰屈服控制奠定了理论基础。
Study on Mn Volatilization Behavior During Vacuum Melting of High-manganese Steel
As an alloying element in steel, manganese can considerably enhance the mechanical properties of structural steel. However, the Mn volatilisation loss in vacuum melting is severe because of the high saturated vapour pressure, resulting in an unstable Mn yield and Mn content fluctuation. Therefore, a systematic study of the volatilisation behaviour of Mn in vacuum melting is required to obtain a suitable Mn control process to achieve precise control of Mn composition, thereby providing a theoretical basis for industrial melting of high-Mn steel. In order to explore the Mn volatilization behavior, the volatilization thermodynamics and volatilisation rate of Mn, as well as the influence factors are discussed in this study. The results shows that Mn is extremely volatilised into the vapour phase under vacuum, the equilibrium partial pressure is closely related to Mn content and temperature. With an increase in the Mn content, a higher C content has a more obvious inhibitory effect on the equilibrium partial pressure of Mn. The maximum theoretical volatilisation rate of Mn shows a linear upward trend with an increase in Mn content. However, a higher C content has a more obvious effect on the reduction of the maximum theoretical volatilisation rate with the increase of Mn content. This study provides an improved understanding of Mn volatilisation behaviour as well as a theoretical foundation for consistent Mn yield control during the vacuum melting process of high-Mn steel.
期刊介绍:
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