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Effect of Composition and Pouring Temperature of Cu-Sn on Fluidity and Mechanical Properties of Investment Casting 铜镍合金成分和浇注温度对熔模铸造流动性和机械性能的影响
IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-22 DOI: 10.24425/afe.2024.151290
S. Slamet, Slamet Khoeron, Ratri Rahmawati, Suyitno, I. Kusumaningtyas
The composition and pouring temperature are important parameters in metal casting. Many cast product failures are caused by ignorance of the influence of both. This research aims to determine the effect of adding tin composition and pouring temperature on fluidity, microstructure and mechanical properties including tensile strength and hardness of tin bronze (Cu-Sn). The Cu-Sn is widely used as employed in the research is Cu (20, 22 and 24) wt.%Sn alloy using the investment casting method. Variations in pouring temperature treatment TS1 = 1000°C and TS2 = 1100°C. The mold for the fluidity test is made with a wax pattern then coated in clay. The mold dimensions are 400 mm long with mold cavity variations of 1.5, 2, 3, 4, 5 mm. Several parameters: increasing the pouring temperature, adding tin composition, decreasing the temperature gradient between the molten metal and the mold walls result in a decrease in the solidification rate which can increase fluidity. The α + δ phase transition to β and γ intermetallic phases decreases fluidity at >22wt.%Sn. The columnar dendrite microstructure increases with the addition of tin composition and pouring temperature. The mechanical properties of tensile strength decrease, hardness increases and the alloy becomes more brittle with increasing tin composition.
成分和浇注温度是金属铸造的重要参数。许多铸造产品失效都是由于忽略了这两个参数的影响。本研究旨在确定加锡成分和浇注温度对锡青铜(Cu-Sn)流动性、微观结构和机械性能(包括抗拉强度和硬度)的影响。研究中广泛使用的 Cu-Sn 是重量百分比为 Cu(20、22 和 24)的锡合金,采用的是熔模铸造法。浇注温度处理 TS1 = 1000°C 和 TS2 = 1100°C。用于流动性测试的模具是用蜡型制作的,然后涂上粘土。模具尺寸为 400 毫米长,模腔变化为 1.5、2、3、4、5 毫米。几个参数:提高浇注温度、添加锡成分、减小熔融金属与模具壁之间的温度梯度,都会导致凝固速率降低,从而增加流动性。当锡含量大于 22wt.% 时,α + δ 相转变为 β 和 γ 金属间相会降低流动性。柱状树枝状微观结构随着锡成分的添加和浇注温度的升高而增加。随着锡成分的增加,拉伸强度、硬度和合金脆性的机械性能均有所下降。
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引用次数: 0
Casting Production in Poland Versus European Trends in 21st Century 波兰的铸造生产与 21 世纪欧洲趋势的对比
IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-22 DOI: 10.24425/afe.2024.151291
M.S. Soiński, A. Jakubus
This article presents changes of the total casting production volumes and of the production of castings made from basic casting alloys in Poland, in Europe and worldwide in years 2001–2021. Analogous casting production parameters were compared for Poland, Europe and countries being the leading European and global manufacturers in years 2001, 2011 and 2021. The leading casting manufacturers in Europe (with the manufacturing volume exceeding 1 million tons in the mentioned years) include Germany, Italy, the Ukraine, France and Spain. For years, the largest casting manufacturer worldwide has been China. In 2001–2021, global casting production increased from ca. 68 million tons to ca. 97 million tons (i.e. by ca. 42%), whereas the European one decreased from ca. 17 million tons to ca. 12 million tons (i.e. by close to 30%). In the analyzed period, the Polish production volume grew from ca. 0.75 million tons to ca. 0.88 million tons (i.e. by ca. 17%). The presented data reveal the decreasing importance of gray cast iron and cast steel and the increasing one of ductile cast iron and aluminum alloys. However, the Polish average annual growth rate for aluminum alloy casting production was 10.3%, whereas the global one was 3% and the European one 0.7%.
这篇文章介绍了2001-2021年波兰、欧洲和全球铸件总产量和基本铸造合金铸件产量的变化。比较了2001年、2011年和2021年波兰、欧洲以及欧洲和全球主要制造商国家的类似铸件生产参数。欧洲主要的铸件制造商(在上述年份的产量超过100万吨)包括德国、意大利、乌克兰、法国和西班牙。多年来,中国一直是全球最大的铸件制造商。2001-2021 年间,全球铸件产量从约 6800 万吨增至约 9700 万吨(增幅约 42%),而欧洲铸件产量则从约 1700 万吨降至约 1200 万吨(降幅近 30%)。在分析期内,波兰的产量从约 75 万吨增长到约 88 万吨(即增长了约 17%)。数据显示,灰铸铁和铸钢的重要性在下降,而球墨铸铁和铝合金的重要性在上升。然而,波兰铝合金铸件生产的平均年增长率为10.3%,而全球为3%,欧洲为0.7%。
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引用次数: 0
Abrasive Wear Resistance of Nodular Cast Iron After Selected Surface Heat and Thermochemical Treatment Processes 经过选定的表面热处理和热化学处理工艺后的球墨铸铁的耐磨损性
IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-19 DOI: 10.24425/afe.2024.151287
C. Baron, M. Stawarz, A. Studnicki, J. Jezierski, T. Wróbel, R. Dojka, M. Lenert, K. Piasecki
The article presents the test results on the technology of surface hardening of castings from unalloyed and low-alloy nodular cast iron using the method of surface heat treatment, i.e., induction surface hardening and methods of thermochemical treatment, i.e. gas nitriding, nitrocarburizing, and nitrocarburizing with oxidation. The scope of research included macro- and microhardness measurements using Rockwell and Vickers methods, respectively, as well as metallographic microscopic examinations using a light microscope. Furthermore, abrasive wear resistance tests were performed using the pin-on-disk method in the friction pair of nodular cast iron – SiC abrasive paper and the reciprocating method in the friction pair of nodular cast iron – unalloyed steel. Analysis of the test results shows that the size and depth of surface layer hardening strongly depend on the chemical composition of the nodular cast iron, determining its hardenability and its ability to create diffusion layers. Medium induction surface hardening made it possible to strengthen the surface layer of the tested nodular cast irons to the level of 700 HV0.5 with a hardening depth of up to approximately 4000μm, while various variants of thermochemical treatment provided surface hardness of up to 750 HV0.5 with a hardening depth of up to approximately 200μm. Furthermore, induction surface hardening increased the resistance to abrasive wear of nodular cast iron castings, depending on the test method, by an average of 70 and 45%, while thermochemical treatment on average by 15 and 60%.
文章介绍了使用表面热处理方法(即感应表面硬化)和热化学处理方法(即气体渗氮、软氮化和氧化软氮化)对非合金和低合金球墨铸铁铸件进行表面硬化的技术试验结果。研究范围包括分别使用洛氏硬度和维氏硬度方法进行宏观和微观硬度测量,以及使用光学显微镜进行金相显微检查。此外,还在球墨铸铁-SiC 砂纸摩擦副中使用了盘上针法,在球墨铸铁-非合金钢摩擦副中使用了往复法,进行了耐磨性测试。对试验结果的分析表明,表面硬化层的大小和深度在很大程度上取决于球墨铸铁的化学成分,决定了其淬透性和形成扩散层的能力。中度感应表面硬化可使受试球墨铸铁的表层强度达到 700 HV0.5,硬化深度可达约 4000μm,而各种热化学处理变体的表面硬度可达 750 HV0.5,硬化深度可达约 200μm。此外,根据不同的测试方法,感应表面硬化可将球墨铸铁铸件的抗磨料磨损性能平均提高 70% 和 45%,而热化学处理可将其平均提高 15% 和 60%。
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引用次数: 0
Comparison of the Mechanical Properties of Ductile Cast Iron Intended for Gas Gate Valves with Nickel Cast Iron with an Austenitic Matrix 气体闸阀用球墨铸铁与奥氏体基体镍铸铁机械性能的比较
IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-19 DOI: 10.24425/afe.2024.151288
A. Rączka, A. Szczęsny, D. Kopyciński, Fabryka Armatur, Jafar S.A. Kadyiego, Street, Jasło, Poland
The study presents a comparison of the results of structural tests, impact strength and strength properties of cast iron EN-GJS-400-15, which is produced in industrial conditions and the ductile cast iron, with addition of nickel, in austenitic matrix. Due to the ongoing energy transformation and attempts to inject hydrogen into existing gas grids, gas fittings manufacturers are looking for materials that will be more resistant to the destructive effects of hydrogen than the currently used ductile cast iron. The aim of the work was to obtain cast iron with the addition of nickel (about 20%) with similar strength parameters, better impact strength, both at room temperature and at lower temperatures, as well as a stable austenitic matrix in ductile cast iron. All assumptions were achieved. In the future, research should be undertaken to develop an economically optimal chemical composition, without a significant loss of strength properties, and the resistance of gate valves made of austenitic cast iron to the destructive effects of hydrogen should be examined. The work is preliminary research.
该研究对在工业条件下生产的铸铁 EN-GJS-400-15 和奥氏体基体中添加了镍的球墨铸铁的结构试验结果、冲击强度和强度特性进行了比较。由于正在进行的能源转型和向现有天然气网注入氢气的尝试,天然气配件制造商正在寻找比目前使用的球墨铸铁更能抵抗氢气破坏作用的材料。这项工作的目的是在球墨铸铁中添加镍(约 20%),使其具有相似的强度参数、更好的冲击强度(无论是在室温还是在较低温度下)以及稳定的奥氏体基体。所有假设均已实现。今后应开展研究,以开发出一种经济上最佳的化学成分,同时不会明显降低强度性能,并应研究奥氏体铸铁制成的闸阀对氢气破坏作用的抵抗力。这项工作属于初步研究。
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引用次数: 0
Kinetic Model for the Decomposition Rate of the Binder in a Foundry Sand Application 铸造砂应用中粘结剂分解率的动力学模型
IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-19 DOI: 10.24425/afe.2024.151289
T. Matsushita, D. Sundaram, I. Belov, A. Diószegi
Accurate kinetic parameters are vital for quantifying the effect of binder decomposition on the complex phenomena occurring during the casting process. Commercial casting simulation tools often use simplified kinetic parameters that do not comprise the complex multiple reactions and their effect on gas generation in the sand core. The present work uses experimental thermal analysis techniques such as Thermogravimetry (TG) and Differential thermal analysis (DTA) to determine the kinetic parameters via approximating the entire reaction during the decomposition by multiple first-order apparent reactions. The TG and DTA results reveal a multi-stage and exothermic decomposition process in the binder degradation. The pressure build-up in cores/molds when using the obtained multi-reaction kinetic model is compared with the earlier approach of using an average model. The results indicate that pressure in the mold/core with the multi-reaction approach is estimated to be significantly higher. These results underscore the importance of precise kinetic parameters for simulating binder decomposition in casting processes.
精确的动力学参数对于量化粘结剂分解对铸造过程中发生的复杂现象的影响至关重要。商业铸造模拟工具通常使用简化的动力学参数,这些参数不包括复杂的多重反应及其对砂芯中气体生成的影响。本研究采用热重分析法(TG)和差热分析法(DTA)等实验热分析技术,通过近似多个一阶表观反应来确定分解过程中的整个反应的动力学参数。TG 和 DTA 结果表明,粘合剂降解过程是一个多阶段的放热分解过程。使用所获得的多反应动力学模型时,型芯/模具中的压力积累情况与之前使用平均模型的方法进行了比较。结果表明,使用多反应方法估计的模具/型芯中的压力要高得多。这些结果强调了精确动力学参数对模拟铸造过程中粘结剂分解的重要性。
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引用次数: 0
Effect of Addition of Ti on Selected Properties of AlSi5Cu2Mg Alloy 添加钛对 AlSi5Cu2Mg 合金某些性能的影响
IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-18 DOI: 10.24425/afe.2024.151285
M. Sýkorová, D. Bolibruchová, M. Brůna, M. Chalupová
The paper focuses on the investigation of the influence of Ti on selected properties of the hypoeutectic aluminium alloy AlSi5Cu2Mg. AlSi5Cu2Mg alloy finds application in the field of production of high-strength cylinder head castings intended for the automotive industry due to the optimal combination of mechanical, physical and foundry properties. In commercial production, the maximum Ti content is limited by the manufacturer (Ti max. = 0.03 wt.%), which significantly limits the possibilities of refinement the alloy with Ti-based grain refiners. Therefore, the possibility of increasing the Ti content beyond the manufacturer's recommendation is considered in this work. The main aim of the work is to evaluate the influence of graded Ti addition (0.1; 0.2; 0.3 wt.% Ti) on the resulting mechanical and physical properties of the AlSi5Cu2Mg alloy. Simultaneously, the influence of increased Ti content on the microstructure of AlSi5Cu2Mg alloy is evaluated. The alloying element was introduced into the melt in the form of AlTi5B1 master alloy. The effect of T6 heat treatment on the resulting mechanical and physical properties and microstructure of the hypoeutectic AlSi5Cu2Mg alloy with graded Ti addition was also investigated in the experimental work.
本文重点研究钛对次共晶铝合金 AlSi5Cu2Mg 某些性能的影响。AlSi5Cu2Mg 合金因其机械、物理和铸造性能的最佳组合而被应用于汽车工业高强度气缸盖铸件的生产领域。在商业生产中,钛的最大含量受到制造商的限制(钛最大含量 = 0.03 wt.%),这大大限制了使用钛基晶粒细化剂细化合金的可能性。因此,本研究考虑了在制造商建议范围之外增加 Ti 含量的可能性。这项工作的主要目的是评估分级添加 Ti(0.1;0.2;0.3 wt.% Ti)对 AlSi5Cu2Mg 合金的机械和物理性能的影响。同时,还评估了钛含量增加对 AlSi5Cu2Mg 合金微观结构的影响。合金元素以 AlTi5B1 母合金的形式引入熔体。实验工作还研究了 T6 热处理对分级添加 Ti 的低共晶 AlSi5Cu2Mg 合金的机械和物理性能以及微观结构的影响。
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引用次数: 0
Utilizing Taguchi method and Regression Analysis for Optimizing Sand Mould Flowability 利用田口方法和回归分析优化砂模流动性
IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-18 DOI: 10.24425/afe.2024.151284
D. Abdulamer, A. Muhsan, Sinan S. Hamdi
Parameters of the moulding process in foundry are usually determined by trial-and-error method, and this way contributes to time taken and adds further cost for production sand. The present work represents an attempt to optimize sand moulding parameters in terms of compactability, compaction time, and air pressure, and to study effect of these factors on the green sand flowability using L4 design of experiments. Regression model, Taguchi method, and experimental verification were used to investigate flow property of sodium bentonite- bonded BP-quartz sand for sand moulding. Analysis of variance (ANOVA) was employed to measure significance and contributions of different moulding variables on flowability of green sand. The values obtained showed that the compaction time factor significantly affected flowability of green sand while compactability and air pressure have slight effects. The comparison results of Taguchi method, regression predictions and experiments exhibited good agreement.
铸造厂的造型工艺参数通常是通过试错法确定的,这种方法既耗时又增加了生产砂的成本。本研究尝试从压实度、压实时间和气压方面优化砂造型参数,并采用 L4 实验设计法研究这些因素对绿砂流动性的影响。采用回归模型、田口方法和实验验证来研究钠基膨润土粘结的 BP-石英砂的流动性能。采用方差分析(ANOVA)来衡量不同造型变量对绿砂流动性的影响。结果表明,压实时间因素对绿砂流动性的影响较大,而压实度和气压的影响较小。田口方法、回归预测和实验的比较结果显示出良好的一致性。
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引用次数: 0
Research of Hybrid Aluminium Castings with the Use of Porous Cores 使用多孔芯材的混合铝铸件研究
IF 0.6 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-18 DOI: 10.24425/afe.2024.151286
M. Brůna, M. Medňanský, P. Oslanec
The paper focuses on the research of hybrid aluminium castings produced by overcasting technology. This is an advanced technology for ensuring the lightness of castings by using the principle of overcasting a core with a porous cellular structure produced by foaming. Process parameters in the foaming phase of the material have a great influence on the resulting porous structure. The article focuses on controlling the influence of pressure during the foaming process on the resulting porosity and evaluating by X-ray tomograph and measuring the relative density. Variants using an initial pressure of 0.3 MPa appear to be the most satisfactory. The challenge of this technology is to ensure adequate bonding of the metals at the interface between the porous core and the solidified metal without penetrating the coating layer. For this reason, the surface treatment of foamed cores with various etchants has been proposed to disrupt the oxide layer on their surface. Macrographs of the uncoated sample and samples etched with 0.5% HF and 10% H3PO4 demonstrated the need for core surface treatment to prevent liquid metal penetration. EDX analysis confirmed the presence of AlPO4 at the core/casting interface in the treated sample.
本文重点研究了利用浇铸技术生产的混合铝铸件。这是一种确保铸件轻量化的先进技术,其原理是利用发泡产生的多孔蜂窝结构包覆芯材。材料发泡阶段的工艺参数对所产生的多孔结构有很大影响。文章的重点是控制发泡过程中的压力对所产生的孔隙率的影响,并通过 X 射线断层扫描和测量相对密度进行评估。使用 0.3 兆帕初始压力的方案似乎最令人满意。这项技术的难点在于如何在不穿透涂层的情况下,确保多孔内核与凝固金属之间的界面充分粘合。因此,有人建议用各种蚀刻剂对发泡芯材进行表面处理,以破坏其表面的氧化层。未涂层样品和用 0.5% HF 和 10% H3PO4 蚀刻过的样品的宏观照片显示,需要对芯材表面进行处理,以防止液态金属渗透。EDX 分析证实,在经过处理的样品中,型芯/铸件界面上存在 AlPO4。
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引用次数: 0
Bio-regeneration for Sodium Silicate Used Sands and its Unattended Monitoring System 硅酸钠废砂的生物再生及其无人值守监控系统
IF 0.6 Q3 Materials Science Pub Date : 2024-06-11 DOI: 10.24425/afe.2024.149278
Huafang Wang, Zhaoxian Jing, Ao Xue, Yuhan Tang, Lei Yang, Jijun Lu
Sodium silicate, known for its low cost and non-toxicity, has been considered as a promising option for green foundry in terms of mould sands. However, the utilization of used sodium silicate sands has posed significant challenges. To address the issues of high energy consumption and secondary pollution associated with wet and dry regeneration of sodium silicate used sands, this paper proposes a novel unattended biological regeneration system. The system involves culturing diatoms in an incubator with a solution of sodium silicate used sands. The incubator is equipped with built-in sensors that continuously monitor temperature, illuminance, pH, and water level. The monitoring data is transmitted in real-time to the Yeelink Internet of Things platform via the controller using the TCP/IP protocol. By logging onto the corresponding web page, the experimenter can remotely observe the monitoring data. The results of the experiment indicate that diatoms bloomed five times, and the water pH decreased from 10.2 to 8.2 after 40 days of cultivation. Additionally, the film removal rate of the used sands reached 90.26%.
硅酸钠以其低成本和无毒性而闻名,一直被认为是绿色铸造中一种很有前途的模砂选择。然而,使用过的硅酸钠砂的利用却面临着巨大的挑战。为解决硅酸钠废砂干湿再生过程中的高能耗和二次污染问题,本文提出了一种新型的无人值守生物再生系统。该系统包括在培养箱中用硅酸钠废砂溶液培养硅藻。培养箱配有内置传感器,可持续监测温度、光照度、pH 值和水位。监测数据通过控制器以 TCP/IP 协议实时传输到 Yeelink 物联网平台。通过登录相应的网页,实验人员可以远程观察监测数据。实验结果表明,经过 40 天的培养,硅藻繁殖了 5 次,水的 pH 值从 10.2 降至 8.2。此外,所用泥沙的除膜率达到了 90.26%。
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引用次数: 0
Decarbonization of Production Systems in Foundries 铸造厂生产系统的去碳化
IF 0.6 Q3 Materials Science Pub Date : 2024-06-11 DOI: 10.24425/afe.2024.149276
C. Kolmasiak
The article discusses the growing importance of decarbonization of production systems in the foundry industry as a response to climate challenges and increasing requirements for sustainable development. The process of reducing greenhouse gas emissions in foundry production is caused by a number of reasons. Decarbonization of the foundry industry refers to actions aimed at reducing greenhouse gas emissions, especially carbon dioxide (CO2). Reducing carbon dioxide emissions is increasingly being considered as a key element of the strategy of both small and large foundries around the world. Foundry is one of the industries that generates significant amounts of carbon dioxide emissions due to the energy consumption in the process of melting and forming metals. There is virtually no manufacturing industry that does not use elements cast from iron, steel or non-ferrous metals, ranging from elements made of aluminum to zinc. The article presents various decarbonization strategies available to foundries, such as: the use of renewable energy, the use of more efficient melting technologies, or the implementation of low-energy technologies throughout the production process. Application examples from different parts of the world illustrate how these strategies are already being put into practice, as well as the potential obstacles and challenges to full decarbonization.
文章讨论了铸造业生产系统去碳化作为应对气候挑战和可持续发展日益增长的要求的日益重要性。铸造生产中减少温室气体排放的过程是由多种原因造成的。铸造业的去碳化是指旨在减少温室气体排放,特别是二氧化碳(CO2)排放的行动。减少二氧化碳排放正日益被视为全球大型和小型铸造厂战略的关键要素。由于金属熔化和成型过程中的能源消耗,铸造业是产生大量二氧化碳排放的行业之一。几乎没有一个制造业不使用铁、钢或有色金属(从铝到锌)铸件。文章介绍了可供铸造厂使用的各种脱碳战略,例如:使用可再生能源、使用更高效的熔炼技术或在整个生产过程中采用低能耗技术。来自世界各地的应用实例说明了这些战略是如何付诸实践的,以及全面去碳化的潜在障碍和挑战。
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引用次数: 0
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Archives of Foundry Engineering
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