在无烟煤中添加碳纳米管,开发高性能锂离子电池负极材料

Jiarong Mai, Shuang Xia, Nan Wang, L. Fu, Lili Liu, Nengfei Yu, Yuping Wu, Rudolf Holze
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摘要

商用石墨负极在锂离子电池(LIB)中面临着制备温度高和比容量有限的问题。无定形碳负极材料制备温度低,制备来源丰富。作为一种低成本的碳源材料,无烟煤作为锂离子电池的负极电极在储锂方面具有实际应用价值。然而,其容量不足以满足目前日益增长的需求。我们添加了碳纳米管,以提高无烟煤基碳阳极的性能。由于无定形碳阳极材料具有良好的电子导电性,因此添加 CNTs 能明显改善其电气性能。这种添加了 CNTs 的无烟煤基碳(A-C)阳极在 LIB 中循环 200 次后,在 200 mA-g-1 的电流密度下显示出 360 mAh-g-1 的比循环容量。我们相信,这项工作对提高无定形碳阳极材料的实用性具有深远意义。
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Adding CNTs into Anthracite towards High Performance Anode Mate­rials for Lithium Ion Batteries
Commercial graphite anodes face the problems of high prepa­ration temperature and limited specific capacity in lithium‐ion batte­ries (LIBs). Amorphous carbon anode materials are prepared at low temperatures and have abundant sources of preparation. As a low‐cost carbon source material, anthracite has a practical applica­tion value in storing lithium as anode electrodes of LIBs. How­ever, the capacity is not enough to meet the present increasing demand. We added CNTs to enhance the performance of anthracite‐based carbon anodes. The addition of CNTs significantly improves the electrical properties of amorphous carbon anode materials due to the good electronic conductivity. This anthracite‐based carbon with CNTs (A‐C) anode displays a specific cycling capacity of 360 mAh·g‐1 at the current density of 200 mA·g‐1 after 200 cycles in LIBs. We believe that the work has far‐reaching significance for improving the practicability of amorphous carbon anode materials.
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