从木质纤维素生物质中提取木质素及其后续用途的高效环保技术:综述

Mohammad Mahbubul Alam , Antonio Greco , Zahra Rajabimashhadi , Carola Esposito Corcione
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引用次数: 0

摘要

开发可持续和有效的木质素提取方法对于实现这些优势和促进向更可持续和循环型生物经济转变至关重要。本研究探讨了使用环境友好型工艺,包括有机溶胶技术、超临界流体 (SCF)、非热等离子体 (NTP)、离子液体 (IL)、深共晶溶剂 (DES) 和微波辅助萃取 (MAE) 技术提取木质素。有机溶胶处理可提供高选择性和高纯度的木质素,使这一工艺具有经济可行性。使用超临界水、二氧化碳或乙醇萃取木质素而不使用有害溶剂,既成功又可定制。NTP 技术可分解木质素,简化加工过程并提高其价值。而 IL 可通过溶剂设计促进木质素合成并改变其特性。基于 DES 的萃取方法可高效、有针对性地提取木质素。快速有效的 MAE 方法利用微波辐射缩短提取时间,提高木质素提取的产量。这些方法具有选择性高、对环境影响小以及可针对木质素馏分的特点。本研究介绍了每种萃取工艺的基本原理、优点和缺点,重点是它们大规模萃取木质素的能力及其未来用途。此外,这篇综述还探讨了应用领域的最新进展,以及萃取过程中产生的液流增值所面临的挑战和潜在优势,从而促进了环境友好型和可持续解决方案的开发。本研究的结论是,要克服未来的挑战,需要解决规模、成本、排放和木质素高效利用等问题。
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Efficient and environmentally friendly techniques for extracting lignin from lignocellulose biomass and subsequent uses: A review

The development of sustainable and effective methods for extracting lignin is crucial for achieving the advantages and promoting the shift towards a more sustainable and circular bioeconomy. This study addresses the use of environmentally friendly processes, including organosolv technique, supercritical fluid (SCF), non-thermal plasma (NTP), ionic liquids (ILs), deep eutectic solvents (DES), and microwave assisted extraction (MAE) techniques for lignin extraction. Organosolv treatment offers high selectivity and purity of lignin make this process economically feasible. Using supercritical water, carbon dioxide, or ethanol to extract lignin without harmful solvents is successful and customizable. NTP technologies break down lignin, simplifying processing and increasing its value. Whereas ILs may boost lignin synthesis and change its properties via solvent design. DES-based extraction methods can efficiently and specifically extract lignin. The rapid and effective MAE method employs microwave radiation to reduce extraction times and boost yields for lignin extraction. These methods feature high selectivity, little environmental impact, and the capacity to target lignin fractions. The study describes the fundamentals, benefits, and drawbacks of each extraction process, focusing on their ability to extract lignin on a large scale and its future usage. Additionally, this review explores the most recent advancements in the application sector, as well as the challenges and potential advantages of valorizing streams derived from extraction, thereby fostering the development of environmentally friendly and sustainable solutions. This research concludes that to overcome future challenges, need to address scale concerns, cost, emissions, and efficient lignin use.

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