硫酸盐还原菌诱导 X80 碳钢在拉伸应力作用下的局部腐蚀和脆性断裂

IF 5.5 3区 材料科学 Q1 ELECTROCHEMISTRY Electrochimica Acta Pub Date : 2024-06-14 DOI:10.1016/j.electacta.2024.144598
Tiansui Zhang , Zixuan Xu , Huihai Wan , Guoqing Wang , Haotian Wu , Xuedong Chen , Hongfang Liu
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引用次数: 0

摘要

研究了在不同拉伸应力和硫酸盐还原菌(SRB)存在的情况下,X80 碳钢受微生物影响的腐蚀(MIC)情况。应力载荷影响了碳钢上的 SRB 无柄细胞数,并对碳钢所受 MIC 的速率产生了重大影响。低于 400 兆帕的应力仅有轻微的促进作用,而接近屈服强度的 550 兆帕应力则明显加速了 SRB 对 X80 碳钢的腐蚀。有限元模拟显示,550 兆帕的弹性应力导致腐蚀凹坑底部应力集中区发生塑性变形,加剧了凹坑中金属的溶解,诱发了二次点蚀。此外,这项研究还证实,SRB 促进了氢向碳钢基体的渗透。高弹性应力和 SRB 的共存使 X80 碳钢更容易发生脆性断裂。
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Localized corrosion and brittle fracture of X80 carbon steel under tensile stress induced by sulfate reducing bacteria

The microbiologically influenced corrosion (MIC) of X80 carbon steel under varying tensile stresses with the presence of sulfate reducing bacteria (SRB) was investigated. The stress loads affected the SRB sessile cell counts on the carbon steel, and exerted a significant influence on the rate of MIC to which the carbon steel was subjected. Stresses below 400 MPa elicited a modest promotion effect, whereas the stress of 550 MPa which was approaching the yield strength markedly expedited the corrosion of SRB on X80 carbon steel. Finite element simulation revealed that the elastic stress of 550 MPa led to plastic deformation in the stress concentration zone at the base of the corrosion pit, exacerbating the dissolution of the metal in pits and inducing secondary pitting corrosion. Additionally, this work confirmed that SRB promoted the permeation of hydrogen into the carbon steel matrix. The coexistence of high elastic stress and SRB rendered X80 carbon steel more prone to brittle fracture.

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来源期刊
Electrochimica Acta
Electrochimica Acta 工程技术-电化学
CiteScore
11.30
自引率
6.10%
发文量
1634
审稿时长
41 days
期刊介绍: Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.
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