Edwin Ino Jung , Hyun Jeong Lee , Jiweon Kim , Qamar Tabrez Siddiqui , Minju Kim , Zhiqun Lin , Cheolmin Park , Dong Ha Kim
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引用次数: 0
摘要
金属卤化物过氧化物(MHPs)作为发光体在发光二极管(LEDs)中的应用引起了广泛关注。自 2009 年首次发现 MHPs 用于太阳能电池应用以来,对其进行了积极的研究。它们显示出优异的光电特性,例如高光致发光量子产率、宽可调带隙、窄发射宽度和高电荷载流子迁移率。手性 MHP 可用作圆偏振发光源、铁电材料、非线性光学材料等。在这篇综述中,我们将讨论手性过氧化物作为发光材料的最新进展及其在下一代 LED 中的应用。手性 MHP 具有手性诱导自旋选择效应的能力,这使其成为自旋偏振 LED 中的高效自旋过滤器。此外,这些 MHP 的手性特性与光电特性相结合,使其成为圆偏振 LED 中发射层的理想材料。本文的全面论述旨在加深对手性 MHP 的自旋光学特性的理解,从而推动手性材料、自旋电子学和基于自旋/CPL 的应用的发展。
Recent progress on chiral perovskites as chiroptical active layers for next-generation LEDs
Metal halide perovskites (MHPs) have drawn intensive attention as emitters for their application in light emitting diodes (LEDs). MHPs have been actively studied after the first discovery in 2009 for solar cell applications. They show excellent optoelectronic properties such as high photoluminescence quantum yields, widely tunable band gap, narrow emission width, and high charge-carrier mobility. Chiral MHPs can be utilized as circularly polarized luminescent sources, ferroelectric materials, nonlinear optical materials, etc. In this review, we discuss the recent progress of chiral perovskites as emitting materials and their applications in next generation LEDs. The ability of chiral MHPs to induce a chiral-induced spin selectivity effect positions them as efficient spin-filters in spin-polarized LEDs. Additionally, the combination of chiral properties and optoelectronic features in these MHPs renders them ideal for use as emissive layers in circularly polarized LEDs. This comprehensive discussion aims to deepen understanding of chiroptical properties in chiral MHPs, furthering the development of chiral materials, chiropto-electronics, and spin/CPL-based applications.
期刊介绍:
Materials Science & Engineering R: Reports is a journal that covers a wide range of topics in the field of materials science and engineering. It publishes both experimental and theoretical research papers, providing background information and critical assessments on various topics. The journal aims to publish high-quality and novel research papers and reviews.
The subject areas covered by the journal include Materials Science (General), Electronic Materials, Optical Materials, and Magnetic Materials. In addition to regular issues, the journal also publishes special issues on key themes in the field of materials science, including Energy Materials, Materials for Health, Materials Discovery, Innovation for High Value Manufacturing, and Sustainable Materials development.