水晶紫修饰的 Fe3O4@Au SERS 探针:高灵敏度的新型 H2 检测方法

IF 5.8 3区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Nanoscale Pub Date : 2024-06-20 DOI:10.1039/d4nr01690d
Dan Xie, Youyou Deng, Xunlong Ji, Yiyan Zhang, Wentao Zhang, Zijin Hong, Wenjing Liu, Jingjing Du, Zhenli Sun
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引用次数: 0

摘要

通过首次将表面增强拉曼散射(SERS)创新性地应用于氢气(H2)检测,在气体检测领域取得了新的突破。这项研究利用了金纳米粒子独特的 SERS 效应以及氢气和紫水晶之间的氧化还原作用,开发出了一种磁性 SERS 探针,其灵敏度和特异性都得到了提高。这种新型探针可以检测到气态环境中低至 1%(体积比)的氢浓度,大大提高了传统氢气报警器的检测限。此外,该报告还全面详细地介绍了 FA-CV 材料的合成、仪器分析以及对 FA-CV 基质 SERS 性能的深入评估,强调了该探针出色的灵敏度、稳定性和可回收性。以这种新颖的方式引入 SERS 不仅为气体传感技术提供了一种有价值的方法,而且还为 SERS 在环境监测和能源安全领域的应用提出了前景广阔的途径,从而说明了这种强大技术的适应性和潜在影响。
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Crystal violet-modified Fe3O4@Au SERS probes: A novel highly sensitive method for H2 detection
A novel breakthrough has been achieved in gas detection through the innovative application of Surface-Enhanced Raman Scattering (SERS) to hydrogen (H2) detection for the first time. This study capitalizes on the unique SERS effects of gold nanoparticles coupled with the redox interaction between hydrogen and crystal violet, allowing for the development of a magnetic SERS probe that demonstrated enhanced sensitivity and specificity. This new probe can detect hydrogen concentrations as low as 1% by volume in gaseous environments, offering a substantial improvement over the detection limits of traditional hydrogen alarms. Further, this report comprehensively detailed the synthesis of the FA-CV materials, instrumental analysis, and an in-depth evaluation of the SERS performance of the FA-CV substrate, underlining the outstanding sensitivity, stability, and recyclability of the probe. The introduction of SERS in this novel capacity not only contributes a valuable approach to gas sensing technologies but, additionally, it suggests promising avenues for the application of SERS in environmental monitoring and energy security, thus, illustrating the adaptability and potential impact of this powerful technique.
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来源期刊
Nanoscale
Nanoscale CHEMISTRY, MULTIDISCIPLINARY-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
12.10
自引率
3.00%
发文量
1628
审稿时长
1.6 months
期刊介绍: Nanoscale is a high-impact international journal, publishing high-quality research across nanoscience and nanotechnology. Nanoscale publishes a full mix of research articles on experimental and theoretical work, including reviews, communications, and full papers.Highly interdisciplinary, this journal appeals to scientists, researchers and professionals interested in nanoscience and nanotechnology, quantum materials and quantum technology, including the areas of physics, chemistry, biology, medicine, materials, energy/environment, information technology, detection science, healthcare and drug discovery, and electronics.
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