Majid Safdari, Daehan Kim, Adam Balvanz, Mercouri G. Kanatzidis
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引用次数: 0
摘要
光诱导的相分离给混合卤化物混合包晶在光伏领域的应用带来了挑战,导致电压不足。在此,我们研究了化学成分在改善宽带隙混合卤化物过氧化物光稳定性方面的作用。我们用七种替代阳离子部分取代了 (Cs0.17FA0.83)Pb(Br0.2I0.8)3 组成中的甲脒阳离子,以实现带隙的轻微蓝移,这通常是通过增加溴化物含量来实现的。在替代阳离子中,二甲基铵(DMA)和乙酰氨基铵(Ac)在浓度为 10%时会诱发更大的蓝移,但不会形成新的低维第二相。光致发光研究分析了所有新成分在高功率激光照射下引起的卤化物偏析,发现 DMA 和 Ac 成分的相偏析减少了。进一步的调整,如增加铯的含量,有效地弥补了带隙中溴化物含量的降低,同时提高了光稳定性。在所有成分中,Cs0.25FA0.65DMA0.1Pb(Br0.2I0.8)3 的光稳定性更强。这些发现凸显了结构改性在生产具有所需带隙的高稳定性成分方面的潜力,为开发稳定的过氧化物太阳能电池铺平了道路。
Mitigation of Halide Segregation by Cation Composition Management in Wide Bandgap Perovskites
Light-induced phase segregation poses challenges for the application of mixed-halide hybrid perovskites in photovoltaics, causing voltage deficits. Here, we investigate the role of chemical composition in improving the photostability of wide bandgap mixed-halide perovskites. We partially substituted the formamidinium cation in the composition of (Cs0.17FA0.83)Pb(Br0.2I0.8)3 with seven alternative cations to achieve a slight blue shift in the bandgap, typically achieved by increasing bromide content. Among alternative cations, dimethylammonium (DMA) and acetamidinium (Ac) induced greater blue shifts at 10% concentration without forming a new low-dimensional second phase. Photoluminescence studies, which analyzed the halide segregation induced by high-power laser irradiation of all new compositions, revealed reduced phase segregation for DMA and Ac compositions. Further adjustments, e.g., increased cesium content, effectively compensated for the lower bromide content in the bandgap while enhancing light stability. Among all compositions, Cs0.25FA0.65DMA0.1Pb(Br0.2I0.8)3 exhibited enhanced photostability. These findings highlight the potential of structural modifications to produce highly stable compositions with the desired bandgap, paving the way for the development of stable perovskite solar cells.
ACS Energy Letters Energy-Renewable Energy, Sustainability and the Environment
CiteScore
31.20
自引率
5.00%
发文量
469
审稿时长
1 months
期刊介绍:
ACS Energy Letters is a monthly journal that publishes papers reporting new scientific advances in energy research. The journal focuses on topics that are of interest to scientists working in the fundamental and applied sciences. Rapid publication is a central criterion for acceptance, and the journal is known for its quick publication times, with an average of 4-6 weeks from submission to web publication in As Soon As Publishable format.
ACS Energy Letters is ranked as the number one journal in the Web of Science Electrochemistry category. It also ranks within the top 10 journals for Physical Chemistry, Energy & Fuels, and Nanoscience & Nanotechnology.
The journal offers several types of articles, including Letters, Energy Express, Perspectives, Reviews, Editorials, Viewpoints and Energy Focus. Additionally, authors have the option to submit videos that summarize or support the information presented in a Perspective or Review article, which can be highlighted on the journal's website. ACS Energy Letters is abstracted and indexed in Chemical Abstracts Service/SciFinder, EBSCO-summon, PubMed, Web of Science, Scopus and Portico.