基于路易斯超酸性硼烷的 9-溴-9-硼芴类似物与路易斯碱的反应研究

IF 3.3 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2024-06-24 DOI:10.1039/D4DT01615G
Libo Xiang, Alexander Matler, Leibo Tan and Qing Ye
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引用次数: 0

摘要

在这篇论文中,我们介绍了 9-溴-9-硼芴的邻硼烷基类似物(一种路易斯超酸)与多种路易斯碱的反应。反应生成了一系列酸碱加合物以及分子内 C-H 活化产物。所有新化合物都已完全定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Reactivity study of Lewis superacidic carborane-based analogue of 9-bromo-9-borafluorene towards Lewis bases†

In this contribution, we present the reactions of the o-carborane-based analogue of 9-bromo-9-borafluorene, a Lewis superacid, with diverse Lewis bases. A range of acid–base adducts, along with an intramolecular C–H activation product, were generated. All new compounds have been fully characterized.

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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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