利用可再生能源实现化工过程的热电气化:经济和去碳化影响

IF 3.8 3区 工程技术 Q2 ENGINEERING, CHEMICAL Industrial & Engineering Chemistry Research Pub Date : 2024-06-25 DOI:10.1021/acs.iecr.4c00737
Ioannis Giannikopoulos, Alkiviadis Skouteris, David T. Allen, Michael Baldea and Mark A. Stadtherr*, 
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引用次数: 0

摘要

近年来,可再生能源对发电组合的贡献不断增加,为化工行业电气化和去碳化提供了新的机遇。然而,可再生能源往往面临着可能影响其最佳利用的挑战。风能和太阳能发电量随时间变化很大,可能导致电力输出与需求不匹配。在这项工作中,我们旨在通过化工生产的直接电气化,特别是用电加热替代化石热加热,找出更有效利用风力发电的最佳方法。我们实施了一个以混合整数线性规划(MILP)形式制定的多周期、多目标优化模型。利润和二氧化碳当量排放被用作竞争目标,以研究可变可再生能源发电的影响,以及如何在化工生产中实现向低碳排放的转变。该模型的功能通过一个流程网络结构来说明,该结构涉及可使用天然气液作为原料的化学流程和一个风力发电场。结果表明,使用可再生电力具有影响力,通过热电气化,可显著减少二氧化碳排放量。化学品和可再生能源电力的共同生产和销售进一步加快了工艺电气化的采用,强调了行业耦合(制造业-电网)在促进去碳化方面的重要性。随着排放限制越来越严格,我们确定了一个过渡点,过了这个过渡点,仅靠热电气化不足以实现排放目标,必须减少产量和/或改变产品组合,以保持最佳利润。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Thermal Electrification of Chemical Processes Using Renewable Energy: Economic and Decarbonization Impacts

The contribution of renewable energy sources to the power generation portfolio has been increasing in recent years, offering new opportunities for chemical industry electrification and decarbonization. However, renewables often face challenges that may affect their optimal utilization. Wind and solar power generation are highly variable over time, which can lead to a mismatch between electricity output and demand. In this work, we aim to identify optimal ways of more efficiently using wind-generated power through the direct electrification of chemical manufacturing, specifically the replacement of fossil-based thermal heating with electricity-based heating. We implement a multiperiod, multiobjective optimization model formulated as a mixed-integer linear program (MILP). Profit and CO2-equivalent emissions are used as competing objectives in an effort to study the impact of variable renewable energy generation and how it can enable the shift toward lower carbon emissions in chemical manufacturing. The model’s capabilities are illustrated using a process network structure involving chemical processes that can use natural gas liquids as raw materials and a wind farm for power generation. The results demonstrate that the use of renewable electricity is impactful and, through thermal electrification, provides significant CO2 emissions reduction. The coproduction and sale of chemicals and renewable electricity are shown to further accelerate the adoption of process electrification, emphasizing the importance of sector coupling (manufacturing–power grid) in promoting decarbonization. As emission limits become stricter, a transition point is identified beyond which thermal electrification alone is insufficient to meet the emissions target, and reductions in production and/or changing the product mix is necessary to maintain an optimal profit.

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来源期刊
Industrial & Engineering Chemistry Research
Industrial & Engineering Chemistry Research 工程技术-工程:化工
CiteScore
7.40
自引率
7.10%
发文量
1467
审稿时长
2.8 months
期刊介绍: ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.
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