二异丙基苯基双亚氨基苊的质子辅助七电子受体特性

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2024-06-26 DOI:10.1039/d4dt01039f

Vera Khrizanforova, Robert R. Fayzullin, Vladimir Morozov, Yulia H Budnikova

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引用次数: 0

摘要

在此，我们报告了在化学和电化学还原条件下，利用质子对二异丙基苯基-双亚氨基苊（dpp-bian）进行六电子还原的破纪录研究。以 dpp-bian-H2 化合物为起始试剂，得到了它的单钠盐和三钠盐。伏安研究表明，三核钠盐在电化学还原过程中可以接受额外的第七个电子。

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Proton-assisted seven-electron acceptor properties of di-iso-propylphenyl-bis-iminoacenaphthene

Herein, we report the record-breaking six-electron reduction of di-iso-propylphenyl-bis-iminoacenaphthene (dpp-bian) involving protons under chemical and electrochemical reduction conditions. Using the dpp-bian-H2 compound as a starting reagent, its mono- and trisodium salts were obtained. A voltammetric study showed that the trinuclear sodium salt can accept an additional seventh electron upon electrochemical reduction.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.