Chenchen Chen , Run Zheng , Lanshan Ye , Fen Yue , Jiaxin Cheng , Juan Wang , Shenran Zhang , Binbin Wu , Pengpeng Lv , Jie Liang , Jun Li
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引用次数: 0
摘要
然而,它的性能不佳、体积膨胀率巨大(∼300%)、薄膜(SEI)不稳定,尤其是对于微米级颗粒而言。我们提出并制备了一种在多孔(p-Si)微粒结构上的新型垂直碳(VG)涂层,它能有效缓解体积膨胀并抑制界面反应。合成的多孔硅 p-Si@VG 复合材料显著增强了循环稳定性,200 次循环后的可逆容量达到 1563 mAh g(容量保持率为 48.6%)。垂直碳纳米片结构构建了三维导电网络。因此,p-Si@VG 复合材料显示出更好的速率能力和更高的锂离子扩散率。这项研究有望推动微米硅基复合材料在.NET领域的应用。
In situ synthesis of vertical graphene on porous Si microparticle composite for high-performance anode material
Silicon is capable of delivering a high theoretical specific capacity (4200 mAh g-1) in lithium-ion batteries. However, silicon has poor electrical conductivity, huge volume expansion (∼300%), and unstable solid electrolyte interface (SEI) film, especially for micron-sized silicon particles. We proposed and prepared a novel vertical carbon (VG) coating on a porous silicon (p-Si) microparticle structure, which effectively alleviated the volume expansion and inhibited the interface reaction. The synthesized porous silicon p-Si@VG composite exhibited significant enhanced cycling stability and an excellent reversible capacity of 1563 mAh g-1 (capacity retention of 48.6%) after 200 cycles. The vertical carbon nanosheet structure constructed a three-dimensional conductive network. Therefore, the p-Si@VG composite showed better rate capability and higher lithium-ion diffusion rates. This work is expected to promote the application of micron Si-based composites in lithium-ion batteries.
期刊介绍:
Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.