工业规模底部燃烧直接还原铁转化工艺的 CFD 模型

IF 3.8 3区 工程技术 Q2 ENGINEERING, CHEMICAL Industrial & Engineering Chemistry Research Pub Date : 2024-06-26 DOI:10.1021/acs.iecr.4c01775
Sirisha Parvathaneni*,  and , Marcelo W. Andrade, 
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引用次数: 0

摘要

在炼铁和炼钢工艺中,直接还原铁(DRI)是使用 CO 和 H2 还原铁矿石的第一步,因此与传统的高炉工艺相比,其二氧化碳排放量更少。DRI 工艺所需的 CO 和 H2 由底部燃烧的转化炉产生,转化炉管内装满催化剂颗粒,然后输送到竖炉进行铁矿石还原。因此,DRI 重整工艺通过提供所需成分、流速和温度的还原气体,在 DRI 生产中发挥着至关重要的作用。在本研究中,开发了一个三维计算流体动力学模型来模拟工业规模的 DRI 重整过程,其中包括反应器管道和燃烧器中的多组分混合气体流动、燃烧器侧燃烧导致的燃烧器到管道的热量传递以及充满催化剂的管道中的重整反应。通过多孔介质方法计算了由于催化剂的存在而导致的管侧压降。结果表明,燃烧在燃烧器一侧形成狭长的火焰,导致管壁和管中心温度升高。这使得管侧发生内热重整反应,消耗 CH4 和 H2O,形成 CO 和 H2。模型预测的管出口重整气体温度和成分以及管壁和管中心不同轴向位置的温度与 ArcelorMittal 工厂的数据完全一致。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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CFD Modeling of the Industrial-Scale Bottom-Fired Direct Reduced Iron Reforming Process

In the iron and steel-making process, direct reduced iron (DRI) is the very first step that uses CO and H2 to reduce iron ore and therefore contributes to fewer CO2 emissions than the conventional blast furnace process. The CO and H2 required for the DRI process are generated from bottom-fired reformers with reformer tubes filled with catalyst particles and transported to the shaft furnace for iron-ore reduction. Therefore, the DRI reforming process plays an essential role in DRI production by supplying reducing gases of the desired composition, flow rate, and temperature. In the present work, a 3D computational fluid dynamics model is developed to simulate the industrial-scale DRI reforming process that includes the multicomponent gas mixture flow in reactor tubes and burners, heat transfer from burner to tubes due to combustion on the burner side, and reforming reactions in catalyst-filled tubes. The pressure drop on the tube side due to the presence of the catalyst is calculated through a porous media approach. Results show the formation of a long and narrow flame on the burner side due to combustion, which led to an increase in the temperature of the tube wall and at the tube center. This enabled endothermic reforming reactions on the tube side and resulted in the consumption of CH4 and H2O and the formation of CO and H2. The model predictions of tube outlet reformed gas temperature and composition and the temperature at different axial locations at the tube wall and center are in satisfactory agreement with ArcelorMittal’s plant data.

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来源期刊
Industrial & Engineering Chemistry Research
Industrial & Engineering Chemistry Research 工程技术-工程:化工
CiteScore
7.40
自引率
7.10%
发文量
1467
审稿时长
2.8 months
期刊介绍: ndustrial & Engineering Chemistry, with variations in title and format, has been published since 1909 by the American Chemical Society. Industrial & Engineering Chemistry Research is a weekly publication that reports industrial and academic research in the broad fields of applied chemistry and chemical engineering with special focus on fundamentals, processes, and products.
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