Yi-Han Liao , Yu-Zhen Lin , Chia-Tzu Kao, Yi-Chun Chen
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Effect of adding curcumin on the characterization of castor oil-based waterborne polyurethane coating
Background
This study investigates the use of curcumin as a hydroxyl chain extender in polyurethane (PU) films, which not only absorbs ultraviolet (UV) light but also acts as a polymeric dye. It evaluates the lightfastness of these films and assesses their potential for wood coating applications.
Methods
Curcumin-based waterborne PU (CPU) resins were prepared by the prepolymerization method using EDA (Ethylenediamine)/curcumin molar ratios of 9/1, 8/2, 7/3, 6/4, and 5/5. The CPU film was analyzed for its transparency, thermal stability, mechanical strength, and water absorption characteristics. In particular, the wood coating performance and lightfastness of the CPU resin were investigated.
Significant findings
The results indicate that higher curcumin content results in an increased proportion of hard segments and hydrogen bonds within the CPU film. Notably, when the EDA/curcumin molar ratio is set to 8/2, the CPU resin exhibits the highest molecular weight, particle size, and cross-linking density, thereby enhancing its tensile strength, Young's modulus, and storage modulus. The results demonstrate the CPU film's ability to absorb UV light, thereby increasing its resistance to light exposure and causing significant color changes in lightfastness tests. CPU resin holds promise for applications as a lightfast yellow coating and a light-sensitive color change indicator.
期刊介绍:
Journal of the Taiwan Institute of Chemical Engineers (formerly known as Journal of the Chinese Institute of Chemical Engineers) publishes original works, from fundamental principles to practical applications, in the broad field of chemical engineering with special focus on three aspects: Chemical and Biomolecular Science and Technology, Energy and Environmental Science and Technology, and Materials Science and Technology. Authors should choose for their manuscript an appropriate aspect section and a few related classifications when submitting to the journal online.