{"title":"硅填充聚丙烯复合材料光氧化老化的界面效应","authors":"Zhiping Xu, Guoshuo Tang, Ying Liu, Rui Yang","doi":"10.1016/j.polymdegradstab.2024.110896","DOIUrl":null,"url":null,"abstract":"<div><p>The nature of the functional groups on the filler surface is one of the key influences on the interfacial interaction in the aging of polymer composites. However, the characteristics of this interfacial effect and its relation with functional groups remain unclear. In this study, we investigated the effects of interfacial interactions on the photooxidative aging of silica-filled polypropylene (PP) composites in which the interfaces comprise functional groups possessing different photooxidative properties. Results showed that the effects of interfacial interactions on the photooxidative aging of the silica-filled PP composites were closely related to the composition of the interfacial functional groups. Since the effect of interfacial interactions on the PP oxidation rate was correlated with the concentration of the interfacial functional groups, an aging kinetic model of interfacial effects could be constructed for determining the role of interfacial functional groups in the photooxidative aging of PP composites. This study will provide new ideas for developing interfacial antioxidant strategies for polymer composites.</p></div>","PeriodicalId":406,"journal":{"name":"Polymer Degradation and Stability","volume":null,"pages":null},"PeriodicalIF":6.3000,"publicationDate":"2024-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0141391024002404/pdfft?md5=92515db0a047b733d10676ec49a2ca8a&pid=1-s2.0-S0141391024002404-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Interfacial effects on photooxidative aging of silica-filled polypropylene composites\",\"authors\":\"Zhiping Xu, Guoshuo Tang, Ying Liu, Rui Yang\",\"doi\":\"10.1016/j.polymdegradstab.2024.110896\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The nature of the functional groups on the filler surface is one of the key influences on the interfacial interaction in the aging of polymer composites. However, the characteristics of this interfacial effect and its relation with functional groups remain unclear. In this study, we investigated the effects of interfacial interactions on the photooxidative aging of silica-filled polypropylene (PP) composites in which the interfaces comprise functional groups possessing different photooxidative properties. Results showed that the effects of interfacial interactions on the photooxidative aging of the silica-filled PP composites were closely related to the composition of the interfacial functional groups. Since the effect of interfacial interactions on the PP oxidation rate was correlated with the concentration of the interfacial functional groups, an aging kinetic model of interfacial effects could be constructed for determining the role of interfacial functional groups in the photooxidative aging of PP composites. This study will provide new ideas for developing interfacial antioxidant strategies for polymer composites.</p></div>\",\"PeriodicalId\":406,\"journal\":{\"name\":\"Polymer Degradation and Stability\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2024-06-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S0141391024002404/pdfft?md5=92515db0a047b733d10676ec49a2ca8a&pid=1-s2.0-S0141391024002404-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Degradation and Stability\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0141391024002404\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Degradation and Stability","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0141391024002404","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Interfacial effects on photooxidative aging of silica-filled polypropylene composites
The nature of the functional groups on the filler surface is one of the key influences on the interfacial interaction in the aging of polymer composites. However, the characteristics of this interfacial effect and its relation with functional groups remain unclear. In this study, we investigated the effects of interfacial interactions on the photooxidative aging of silica-filled polypropylene (PP) composites in which the interfaces comprise functional groups possessing different photooxidative properties. Results showed that the effects of interfacial interactions on the photooxidative aging of the silica-filled PP composites were closely related to the composition of the interfacial functional groups. Since the effect of interfacial interactions on the PP oxidation rate was correlated with the concentration of the interfacial functional groups, an aging kinetic model of interfacial effects could be constructed for determining the role of interfacial functional groups in the photooxidative aging of PP composites. This study will provide new ideas for developing interfacial antioxidant strategies for polymer composites.
期刊介绍：
Polymer Degradation and Stability deals with the degradation reactions and their control which are a major preoccupation of practitioners of the many and diverse aspects of modern polymer technology.
Deteriorative reactions occur during processing, when polymers are subjected to heat, oxygen and mechanical stress, and during the useful life of the materials when oxygen and sunlight are the most important degradative agencies. In more specialised applications, degradation may be induced by high energy radiation, ozone, atmospheric pollutants, mechanical stress, biological action, hydrolysis and many other influences. The mechanisms of these reactions and stabilisation processes must be understood if the technology and application of polymers are to continue to advance. The reporting of investigations of this kind is therefore a major function of this journal.
However there are also new developments in polymer technology in which degradation processes find positive applications. For example, photodegradable plastics are now available, the recycling of polymeric products will become increasingly important, degradation and combustion studies are involved in the definition of the fire hazards which are associated with polymeric materials and the microelectronics industry is vitally dependent upon polymer degradation in the manufacture of its circuitry. Polymer properties may also be improved by processes like curing and grafting, the chemistry of which can be closely related to that which causes physical deterioration in other circumstances.
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