Shuai Cui , Haimin Zhai , Wei Tong , Wensheng Li , Xuqiang Li , Xiangjuan Fan , Dangsheng Xiong
{"title":"NaCl溶液中铁基无定形涂层的钝化行为和表面化学性质:外加电位和浸泡时间的影响","authors":"Shuai Cui , Haimin Zhai , Wei Tong , Wensheng Li , Xuqiang Li , Xiangjuan Fan , Dangsheng Xiong","doi":"10.1016/j.intermet.2024.108391","DOIUrl":null,"url":null,"abstract":"<div><p>The influence of the potential for film formation and immersion time on the corrosion resistance of the passive film formed on Fe-based amorphous coating was thoroughly investigated. The semiconducting properties and chemical composition of the passive films were analyzed employing Mott-Schottky and XPS techniques. Results indicate that the stability of the film diminished as the potentials and immersion periods increased. The structural properties and chemical composition of film played a crucial role in the corrosion resistance of the coating in a chloride electrolyte. The accumulation of cation vacancies and the formation of metal chlorides increased the likelihood of film rupture, ultimately leading to pitting.</p></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Passivation behavior and surface chemistry of Fe-based amorphous coating in NaCl solution: Influence of applied potential and immersion time\",\"authors\":\"Shuai Cui , Haimin Zhai , Wei Tong , Wensheng Li , Xuqiang Li , Xiangjuan Fan , Dangsheng Xiong\",\"doi\":\"10.1016/j.intermet.2024.108391\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The influence of the potential for film formation and immersion time on the corrosion resistance of the passive film formed on Fe-based amorphous coating was thoroughly investigated. The semiconducting properties and chemical composition of the passive films were analyzed employing Mott-Schottky and XPS techniques. Results indicate that the stability of the film diminished as the potentials and immersion periods increased. The structural properties and chemical composition of film played a crucial role in the corrosion resistance of the coating in a chloride electrolyte. The accumulation of cation vacancies and the formation of metal chlorides increased the likelihood of film rupture, ultimately leading to pitting.</p></div>\",\"PeriodicalId\":331,\"journal\":{\"name\":\"Intermetallics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-06-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Intermetallics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0966979524002103\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Intermetallics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0966979524002103","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Passivation behavior and surface chemistry of Fe-based amorphous coating in NaCl solution: Influence of applied potential and immersion time
The influence of the potential for film formation and immersion time on the corrosion resistance of the passive film formed on Fe-based amorphous coating was thoroughly investigated. The semiconducting properties and chemical composition of the passive films were analyzed employing Mott-Schottky and XPS techniques. Results indicate that the stability of the film diminished as the potentials and immersion periods increased. The structural properties and chemical composition of film played a crucial role in the corrosion resistance of the coating in a chloride electrolyte. The accumulation of cation vacancies and the formation of metal chlorides increased the likelihood of film rupture, ultimately leading to pitting.
期刊介绍:
This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys.
The journal reports the science and engineering of metallic materials in the following aspects:
Theories and experiments which address the relationship between property and structure in all length scales.
Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations.
Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties.
Technological applications resulting from the understanding of property-structure relationship in materials.
Novel and cutting-edge results warranting rapid communication.
The journal also publishes special issues on selected topics and overviews by invitation only.