Changhao Tian , Mengyuan Song , Haoyang Yuan , Wenjun Lin , Chao Ai , Huajun Cao , Tao Huang , Aishui Yu
{"title":"用于高压锂金属电池的双层 Janus 固体电解质的合理设计","authors":"Changhao Tian , Mengyuan Song , Haoyang Yuan , Wenjun Lin , Chao Ai , Huajun Cao , Tao Huang , Aishui Yu","doi":"10.1016/j.jpowsour.2024.234920","DOIUrl":null,"url":null,"abstract":"<div><p>Interfacial side reaction is a major problem faced by solid state electrolyte (SSE), especially the oxidation reaction between high-voltage cathode materials and SSE. Herein, a double-layer PVCA-ETPTA|LAGP-PPC Janus solid electrolyte (JSE) with ultra-high interfacial stability is successfully designed. An oxidation tolerant cross-linked poly (Vinylene Carbonate) (PVCA)-Ethoxylated trimethylolpropane triacrylate (ETPTA) electrolyte is used on the cathode side, resulting in a stable interfacial layer under high-voltage. To enhance the stability of SSE|Li interface, a protective Li<sub>1.5</sub>Al<sub>0.5</sub>Ge<sub>1.5</sub>P<sub>3</sub>O<sub>12</sub> (LAGP)-Poly (propylene carbonate) (PPC) layer is adhered to Li metal. The obtained dual-layer structure shows great thermal stability with an electrochemical stable window of 0–4.5 V. Moreover, the PVCA-ETPTA layer fabricated by in-situ polymerization helps building an integrated structure, which can significantly reduce the interfacial resistance. The ionic conductivity of LP|PE can reach 1.2 × 10<sup>−4</sup> S cm<sup>−1</sup> at 55 °C. As a consequence, the assembled NCM622|LP|PE|Li solid state cell shows exceptional electrochemical performance, with 70 % cycle retention for 100 cycles at 0.2 C.</p></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":null,"pages":null},"PeriodicalIF":8.1000,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rational design of a double-layer Janus solid electrolyte for high voltage lithium metal battery\",\"authors\":\"Changhao Tian , Mengyuan Song , Haoyang Yuan , Wenjun Lin , Chao Ai , Huajun Cao , Tao Huang , Aishui Yu\",\"doi\":\"10.1016/j.jpowsour.2024.234920\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Interfacial side reaction is a major problem faced by solid state electrolyte (SSE), especially the oxidation reaction between high-voltage cathode materials and SSE. Herein, a double-layer PVCA-ETPTA|LAGP-PPC Janus solid electrolyte (JSE) with ultra-high interfacial stability is successfully designed. An oxidation tolerant cross-linked poly (Vinylene Carbonate) (PVCA)-Ethoxylated trimethylolpropane triacrylate (ETPTA) electrolyte is used on the cathode side, resulting in a stable interfacial layer under high-voltage. To enhance the stability of SSE|Li interface, a protective Li<sub>1.5</sub>Al<sub>0.5</sub>Ge<sub>1.5</sub>P<sub>3</sub>O<sub>12</sub> (LAGP)-Poly (propylene carbonate) (PPC) layer is adhered to Li metal. The obtained dual-layer structure shows great thermal stability with an electrochemical stable window of 0–4.5 V. Moreover, the PVCA-ETPTA layer fabricated by in-situ polymerization helps building an integrated structure, which can significantly reduce the interfacial resistance. The ionic conductivity of LP|PE can reach 1.2 × 10<sup>−4</sup> S cm<sup>−1</sup> at 55 °C. As a consequence, the assembled NCM622|LP|PE|Li solid state cell shows exceptional electrochemical performance, with 70 % cycle retention for 100 cycles at 0.2 C.</p></div>\",\"PeriodicalId\":377,\"journal\":{\"name\":\"Journal of Power Sources\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.1000,\"publicationDate\":\"2024-06-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Power Sources\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0378775324008723\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Power Sources","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0378775324008723","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
界面副反应是固态电解质(SSE)面临的主要问题,尤其是高压阴极材料与 SSE 之间的氧化反应。本文成功设计了一种具有超高界面稳定性的双层 PVCA-ETPTA|LAGP-PPC Janus 固体电解质(JSE)。阴极侧使用了耐氧化的交联聚(碳酸乙烯酯)(PVCA)-乙氧基化三羟甲基丙烷三丙烯酸酯(ETPTA)电解质,从而在高压下形成了稳定的界面层。为了增强 SSE|Li 界面的稳定性,Li 金属上附着了一层 Li1.5Al0.5Ge1.5P3O12 (LAGP)-Poly (propylene carbonate) (PPC) 保护层。所获得的双层结构具有很高的热稳定性和 0-4.5 V 的电化学稳定窗口。此外,通过原位聚合制造的 PVCA-ETPTA 层有助于构建一体化结构,从而显著降低界面电阻。在 55 °C 时,LP|PE 的离子电导率可达 1.2 × 10-4 S cm-1。因此,组装好的 NCM622|LP|PE|锂固态电池显示出卓越的电化学性能,在 0.2 C 温度下循环 100 次可保持 70% 的循环率。
Rational design of a double-layer Janus solid electrolyte for high voltage lithium metal battery
Interfacial side reaction is a major problem faced by solid state electrolyte (SSE), especially the oxidation reaction between high-voltage cathode materials and SSE. Herein, a double-layer PVCA-ETPTA|LAGP-PPC Janus solid electrolyte (JSE) with ultra-high interfacial stability is successfully designed. An oxidation tolerant cross-linked poly (Vinylene Carbonate) (PVCA)-Ethoxylated trimethylolpropane triacrylate (ETPTA) electrolyte is used on the cathode side, resulting in a stable interfacial layer under high-voltage. To enhance the stability of SSE|Li interface, a protective Li1.5Al0.5Ge1.5P3O12 (LAGP)-Poly (propylene carbonate) (PPC) layer is adhered to Li metal. The obtained dual-layer structure shows great thermal stability with an electrochemical stable window of 0–4.5 V. Moreover, the PVCA-ETPTA layer fabricated by in-situ polymerization helps building an integrated structure, which can significantly reduce the interfacial resistance. The ionic conductivity of LP|PE can reach 1.2 × 10−4 S cm−1 at 55 °C. As a consequence, the assembled NCM622|LP|PE|Li solid state cell shows exceptional electrochemical performance, with 70 % cycle retention for 100 cycles at 0.2 C.
期刊介绍:
The Journal of Power Sources is a publication catering to researchers and technologists interested in various aspects of the science, technology, and applications of electrochemical power sources. It covers original research and reviews on primary and secondary batteries, fuel cells, supercapacitors, and photo-electrochemical cells.
Topics considered include the research, development and applications of nanomaterials and novel componentry for these devices. Examples of applications of these electrochemical power sources include:
• Portable electronics
• Electric and Hybrid Electric Vehicles
• Uninterruptible Power Supply (UPS) systems
• Storage of renewable energy
• Satellites and deep space probes
• Boats and ships, drones and aircrafts
• Wearable energy storage systems