{"title":"用于锂金属电池的双 MOFs 笼构造多级通道 PVDF-HFP 准固体电解质","authors":"Jiangchao Chen, Hu Wang, Yiran Bai, Pengfei Pang, Zhiqiang Zheng, Huarui Xu, Yunyun Zhao, Kunpeng Jiang, Guisheng Zhu","doi":"10.1016/j.jpowsour.2024.234973","DOIUrl":null,"url":null,"abstract":"<div><p>As the candidate for electrolyte in lithium metal batteries, quasi-solid electrolytes have been affected by the growth of lithium dendrites and the continuous reaction between lithium and electrolyte. Herein, we introduce a quasi-solid electrolyte, ZIF-67@ZIF-8/PVDF-HFP (PHMx), with multi-stage ion transport channels. Additionally, we have developed Zeolitic Imidazolate Frameworks (ZIFs) materials that possess a “cage” structure, which is defined as dual-MC nanoparticles. PVDF-HFP in PHMx serves as mechanical backbone, with dual-MC nanoparticles densely and uniformly distributed within the PVDF-HFP. The synergistic effect of the microporous structure of the PVDF-HFP and that of the dual-MC nanoparticles is utilized to construct multi-stage ion transport channels. PHM9 achieves uniform Li<sup>+</sup> deposition and inhibits the continuous reaction between lithium and electrolyte. Therefore, PHM9, not only achieves high ionic conductivity of 3.2 × 10<sup>−3</sup> S cm<sup>−1</sup> but also remains stable for 1600 h during Lithium-symmetric cycling. Lithium metal battery, assembled with LiFePO<sub>4</sub> as the cathode material, exhibited stable cycling for 400 cycles at a rate of 0.2 C, demonstrating a capacity retention rate of 86.6 %. Similarly, the lithium metal battery utilizing LiCoO<sub>2</sub> as the cathode material demonstrated stable cycling for 200 cycles at a rate of 0.2 C, exhibiting an impressive capacity retention rate of 96.7 %.</p></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":null,"pages":null},"PeriodicalIF":8.1000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dual-MOFs-cage constructed multistage-channel PVDF-HFP quasi-solid electrolytes for lithium metal battery\",\"authors\":\"Jiangchao Chen, Hu Wang, Yiran Bai, Pengfei Pang, Zhiqiang Zheng, Huarui Xu, Yunyun Zhao, Kunpeng Jiang, Guisheng Zhu\",\"doi\":\"10.1016/j.jpowsour.2024.234973\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>As the candidate for electrolyte in lithium metal batteries, quasi-solid electrolytes have been affected by the growth of lithium dendrites and the continuous reaction between lithium and electrolyte. Herein, we introduce a quasi-solid electrolyte, ZIF-67@ZIF-8/PVDF-HFP (PHMx), with multi-stage ion transport channels. Additionally, we have developed Zeolitic Imidazolate Frameworks (ZIFs) materials that possess a “cage” structure, which is defined as dual-MC nanoparticles. PVDF-HFP in PHMx serves as mechanical backbone, with dual-MC nanoparticles densely and uniformly distributed within the PVDF-HFP. The synergistic effect of the microporous structure of the PVDF-HFP and that of the dual-MC nanoparticles is utilized to construct multi-stage ion transport channels. PHM9 achieves uniform Li<sup>+</sup> deposition and inhibits the continuous reaction between lithium and electrolyte. Therefore, PHM9, not only achieves high ionic conductivity of 3.2 × 10<sup>−3</sup> S cm<sup>−1</sup> but also remains stable for 1600 h during Lithium-symmetric cycling. Lithium metal battery, assembled with LiFePO<sub>4</sub> as the cathode material, exhibited stable cycling for 400 cycles at a rate of 0.2 C, demonstrating a capacity retention rate of 86.6 %. Similarly, the lithium metal battery utilizing LiCoO<sub>2</sub> as the cathode material demonstrated stable cycling for 200 cycles at a rate of 0.2 C, exhibiting an impressive capacity retention rate of 96.7 %.</p></div>\",\"PeriodicalId\":377,\"journal\":{\"name\":\"Journal of Power Sources\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.1000,\"publicationDate\":\"2024-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Power Sources\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S037877532400925X\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Power Sources","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S037877532400925X","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
作为锂金属电池的候选电解质,准固体电解质一直受到锂枝晶生长以及锂与电解质之间连续反应的影响。在此,我们介绍一种具有多级离子传输通道的准固体电解质 ZIF-67@ZIF-8/PVDF-HFP (PHMx)。此外,我们还开发了具有 "笼状 "结构的沸石咪唑啉框架(ZIFs)材料,它被定义为双 MC 纳米粒子。PHMx 中的 PVDF-HFP 充当机械骨架,双 MC 纳米粒子密集均匀地分布在 PVDF-HFP 中。利用 PVDF-HFP 的微孔结构和双 MC 纳米粒子的微孔结构的协同效应,构建了多级离子传输通道。PHM9 实现了 Li+ 的均匀沉积,并抑制了锂与电解液之间的持续反应。因此,PHM9 不仅实现了 3.2 × 10-3 S cm-1 的高离子电导率,还能在锂对称循环中保持 1600 小时的稳定性。以 LiFePO4 为正极材料组装的锂金属电池在 0.2 C 的条件下稳定循环 400 次,容量保持率达 86.6%。同样,使用钴酸锂作为正极材料的锂金属电池在 0.2 摄氏度的条件下稳定循环 200 次,容量保持率高达 96.7%。
Dual-MOFs-cage constructed multistage-channel PVDF-HFP quasi-solid electrolytes for lithium metal battery
As the candidate for electrolyte in lithium metal batteries, quasi-solid electrolytes have been affected by the growth of lithium dendrites and the continuous reaction between lithium and electrolyte. Herein, we introduce a quasi-solid electrolyte, ZIF-67@ZIF-8/PVDF-HFP (PHMx), with multi-stage ion transport channels. Additionally, we have developed Zeolitic Imidazolate Frameworks (ZIFs) materials that possess a “cage” structure, which is defined as dual-MC nanoparticles. PVDF-HFP in PHMx serves as mechanical backbone, with dual-MC nanoparticles densely and uniformly distributed within the PVDF-HFP. The synergistic effect of the microporous structure of the PVDF-HFP and that of the dual-MC nanoparticles is utilized to construct multi-stage ion transport channels. PHM9 achieves uniform Li+ deposition and inhibits the continuous reaction between lithium and electrolyte. Therefore, PHM9, not only achieves high ionic conductivity of 3.2 × 10−3 S cm−1 but also remains stable for 1600 h during Lithium-symmetric cycling. Lithium metal battery, assembled with LiFePO4 as the cathode material, exhibited stable cycling for 400 cycles at a rate of 0.2 C, demonstrating a capacity retention rate of 86.6 %. Similarly, the lithium metal battery utilizing LiCoO2 as the cathode material demonstrated stable cycling for 200 cycles at a rate of 0.2 C, exhibiting an impressive capacity retention rate of 96.7 %.
期刊介绍:
The Journal of Power Sources is a publication catering to researchers and technologists interested in various aspects of the science, technology, and applications of electrochemical power sources. It covers original research and reviews on primary and secondary batteries, fuel cells, supercapacitors, and photo-electrochemical cells.
Topics considered include the research, development and applications of nanomaterials and novel componentry for these devices. Examples of applications of these electrochemical power sources include:
• Portable electronics
• Electric and Hybrid Electric Vehicles
• Uninterruptible Power Supply (UPS) systems
• Storage of renewable energy
• Satellites and deep space probes
• Boats and ships, drones and aircrafts
• Wearable energy storage systems