{"title":"二氧化碳(+H2)流中的铜渗入 Ni-YSZ 阴极:反向水气变换与二氧化碳电解","authors":"Vipin Kamboj, Chinmoy Ranjan","doi":"10.1016/j.jpowsour.2024.234985","DOIUrl":null,"url":null,"abstract":"<div><p>Ni-Yttria Stabilized Zirconia (Ni-YSZ) cermet electrode is known to perform in CO<sub>2</sub> (+H<sub>2</sub>) stream. Introducing H<sub>2</sub> in CO<sub>2</sub> containing streams enables thermochemical reverse water gas shift reaction (rWGS: CO<sub>2</sub> + H<sub>2</sub> → CO + H<sub>2</sub>O) at open circuit. Without the application of any bias, the rWGS responds positively to an increase in temperature and concentrations of CO<sub>2</sub> and H<sub>2</sub>. Application of bias results in enhancement in CO yield above the rWGS baseline value. With bias, both CO<sub>2</sub> and H<sub>2</sub>O electrolysis are enabled. The infiltration of Cu on the Ni-YSZ backbone results in significant improvement of the reaction kinetics and increases H<sub>2</sub> and CO production. Impedance analysis indicates that the kinetic limitation originates from reaction steps with slower time constants with Ni{Cu}<sub>x</sub>-YSZ outperforming Ni-YSZ in this aspect. Cu infiltration suppresses particle coarsening typically observed in Ni-YSZ.</p></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":null,"pages":null},"PeriodicalIF":8.1000,"publicationDate":"2024-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Cu infiltrated Ni-YSZ cathode in CO2 (+H2) stream: Reverse water gas shift vs. CO2 electrolysis\",\"authors\":\"Vipin Kamboj, Chinmoy Ranjan\",\"doi\":\"10.1016/j.jpowsour.2024.234985\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Ni-Yttria Stabilized Zirconia (Ni-YSZ) cermet electrode is known to perform in CO<sub>2</sub> (+H<sub>2</sub>) stream. Introducing H<sub>2</sub> in CO<sub>2</sub> containing streams enables thermochemical reverse water gas shift reaction (rWGS: CO<sub>2</sub> + H<sub>2</sub> → CO + H<sub>2</sub>O) at open circuit. Without the application of any bias, the rWGS responds positively to an increase in temperature and concentrations of CO<sub>2</sub> and H<sub>2</sub>. Application of bias results in enhancement in CO yield above the rWGS baseline value. With bias, both CO<sub>2</sub> and H<sub>2</sub>O electrolysis are enabled. The infiltration of Cu on the Ni-YSZ backbone results in significant improvement of the reaction kinetics and increases H<sub>2</sub> and CO production. Impedance analysis indicates that the kinetic limitation originates from reaction steps with slower time constants with Ni{Cu}<sub>x</sub>-YSZ outperforming Ni-YSZ in this aspect. Cu infiltration suppresses particle coarsening typically observed in Ni-YSZ.</p></div>\",\"PeriodicalId\":377,\"journal\":{\"name\":\"Journal of Power Sources\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.1000,\"publicationDate\":\"2024-06-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Power Sources\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0378775324009376\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Power Sources","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0378775324009376","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
众所周知,镍钇稳定氧化锆(Ni-YSZ)金属陶瓷电极在二氧化碳(+H2)气流中性能良好。在含有二氧化碳的气流中引入 H2,可在开路状态下发生热化学反向水气变换反应(rWGS:CO2 + H2 → CO + H2O)。在不施加任何偏压的情况下,rWGS 会对温度的升高以及 CO2 和 H2 浓度的增加做出积极反应。施加偏压后,一氧化碳的产量会高于 rWGS 的基线值。施加偏压后,二氧化碳和 H2O 电解均可进行。在 Ni-YSZ 骨架上渗入铜可显著改善反应动力学,提高 H2 和 CO 的产量。阻抗分析表明,动力学限制源于时间常数较慢的反应步骤,Ni{Cu}x-YSZ 在这方面的表现优于 Ni-YSZ。铜的渗入抑制了通常在 Ni-YSZ 中观察到的颗粒粗化现象。
Cu infiltrated Ni-YSZ cathode in CO2 (+H2) stream: Reverse water gas shift vs. CO2 electrolysis
Ni-Yttria Stabilized Zirconia (Ni-YSZ) cermet electrode is known to perform in CO2 (+H2) stream. Introducing H2 in CO2 containing streams enables thermochemical reverse water gas shift reaction (rWGS: CO2 + H2 → CO + H2O) at open circuit. Without the application of any bias, the rWGS responds positively to an increase in temperature and concentrations of CO2 and H2. Application of bias results in enhancement in CO yield above the rWGS baseline value. With bias, both CO2 and H2O electrolysis are enabled. The infiltration of Cu on the Ni-YSZ backbone results in significant improvement of the reaction kinetics and increases H2 and CO production. Impedance analysis indicates that the kinetic limitation originates from reaction steps with slower time constants with Ni{Cu}x-YSZ outperforming Ni-YSZ in this aspect. Cu infiltration suppresses particle coarsening typically observed in Ni-YSZ.
期刊介绍:
The Journal of Power Sources is a publication catering to researchers and technologists interested in various aspects of the science, technology, and applications of electrochemical power sources. It covers original research and reviews on primary and secondary batteries, fuel cells, supercapacitors, and photo-electrochemical cells.
Topics considered include the research, development and applications of nanomaterials and novel componentry for these devices. Examples of applications of these electrochemical power sources include:
• Portable electronics
• Electric and Hybrid Electric Vehicles
• Uninterruptible Power Supply (UPS) systems
• Storage of renewable energy
• Satellites and deep space probes
• Boats and ships, drones and aircrafts
• Wearable energy storage systems