Shan Wang, Jiarui Yang, Wenrui Cai, Guojiang Wen, Sifan Yang, Kai Ke, Bo Yin, Xuewei Fu, Wei Yang, Yu Wang
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A Polymer‐Sol Binder Realizes Single‐Particle Binding for Nacre‐Like Piezoelectric Nanocomposites and Component‐Integrated Batteries
Achieving precisely defined and stable component binding is of great interest for composite materials and batteries, but very challenging owing to the lack of effective strategies to manipulate the binder itself. Here, a concept of single‐particle binding (SPB) strategy is proposed based on a polymer‐sol binder to conquer the above challenge. To do that, a polymer‐sol binder is first prepared by dispersing commercial poly(vinylidene fluoride) (PVDF) powder into a mixture of its solvent and non‐solvent with a rational weight ratio of 8:2. Then, by manipulating this PVDF‐sol microfluid, PVDF particles are uniformly and singly introduced onto the surface of other components, such as graphene oxide nanosheets and battery separators. Results further show that the temperature‐induced sol–gel transition of the microfluid finally generates single‐particle fusion and strong component binding with commercial separators (31.6 N m−1). Meanwhile, a surface‐swelling model is proposed to understand its binding mechanism. Finally, this unique SPB strategy has been employed to fabricate nacre‐like nanocomposites with advanced self‐polarized piezoelectricity (23.0 mV N−1), and component‐integrated batteries with robust separator/electrode interphases. This SPB strategy with the PVDF‐sol binder may inspire significant studies on polymer sol, microfluidics, nanocomposites, battery interfaces and beyond.
期刊介绍:
Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small.
With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics.
The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.