混合润湿纳米级页岩垫层断裂中石油输送的发生和流动行为。

IF 3.7 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Langmuir Pub Date : 2024-07-03 DOI:10.1021/acs.langmuir.4c00983
Yuhan Wang, Zhengdong Lei, Zhenhua Xu, Yishan Liu, Qiang Zhou and Pengcheng Liu*, 
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引用次数: 0

摘要

页岩储层的特点是存在大量纳米级孔隙和微裂缝。由于传统的渗流数学模型不足以准确描述这些现象,因此有必要对纳米约束空间内的流体发生状态和流动行为采用新的研究方法。本研究以中国古龙页岩储层为研究对象。首先,利用实际的微孔图像研究并描述了古龙页岩储层独特的混合润湿特征。随后,通过微观孔隙图像和分子动力学模拟相结合的方法,描述了各种润湿情况下石油在纳米级垫层裂缝中的发生和流动行为。最终建立了一个数学模型,描述了石油的速度分布及其表观渗透率。该研究结果表明,当页岩垫层裂缝的尺度小于 100 纳米时,纳米孔隙效应的影响非常显著,不容忽视。在这种情况下,油的发生状态及其流动行为受到混合润湿壁上初始油湿表面积的影响。该研究通过数学模型量化了混合润湿纳米尺度页岩垫层裂缝中石油的速度和密度分布,为从纳米尺度上升到宏观尺度提供了重要的理论基础。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Occurrence and Flow Behavior for Oil Transport in Mixed Wetting Nanoscale Shale Bedding Fractures

Shale reservoirs are characterized by an abundance of nanoscale porosities and microfractures. The states of fluid occurrence and flow behaviors within nanoconfined spaces necessitate novel research approaches, as traditional percolation mathematical models are inadequate for accurately depicting these phenomena. This study takes the Gulong shale reservoir in China as the subject of its research. Initially, the unique mixed wetting characteristics of the Gulong shale reservoir are examined and characterized using actual micropore images. Subsequently, the occurrence and flow behavior of oil within the nanoscale bedding fractures under various wettability scenarios are described through a combination of microscopic pore image and molecular dynamics simulations. Ultimately, a mathematical model is established that depicts the velocity distribution of oil and its apparent permeability. This study findings indicate that when the scale of the shale bedding fractures is less than 100 nm, the impact of the nanoconfinement effect is significant and cannot be overlooked. In this scenario, the state of oil occurrence and its flow behavior are influenced by the initial oil-wet surface area on the mixed wetting walls. The study quantifies the velocity and density distribution of oil in mixed wetting nanoscale shale bedding fractures through a mathematical model, providing a crucial theoretical basis for upscaling from the nanoscale to the macroscale.

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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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