从地幔源到地壳汇:芬兰拉普兰中部绿岩带古生代科马蒂岩的岩浆分异和硫化物饱和度

IF 3.5 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Contributions to Mineralogy and Petrology Pub Date : 2024-06-26 DOI:10.1007/s00410-024-02154-9
Ville J. Virtanen, Henri M.A. Höytiä, Giada Iacono-Marziano, Shenghong Yang, Marko Moilanen, Tuomo Törmänen
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引用次数: 0

摘要

在芬兰北部的拉普兰中部绿岩带(CLGB),广泛分布着古近纪(2.05 Ga)的孔雀石。这些孔雀石与富含硫(S)的乡土岩密切相关,并与凯维察(Kevitsa)和萨卡蒂(Sakatti)的铜镍(-PGE)矿床存在时空联系,因此是硫化物矿床勘探的有趣目标。我们提供了 Sattasvaara 星岩的全岩地球化学数据,并将其与文献数据相结合,形成了 CLGB 星岩的地球化学数据库。我们构建了一个从地幔源绝热熔融到地壳条件下部分结晶的孔雀石模型。利用 MELTS,我们计算了 CLGB 共陨石与 Fo92、Fo93 和 Fo94 橄榄石处于平衡状态的三种母熔体(MgO = 20.6-25.7 wt%)。根据REEBOX PRO模拟,当潜在温度为1575-1700 °C时,这些母体熔体可以通过不同的压力和熔化程度从单一地幔源形成。我们根据不同的地幔熔融条件和熔融程度,计算出了母熔体的 S 含量范围。我们使用岩浆室模拟器在地壳条件下对母体熔体进行分馏结晶。这些模拟再现了我们的光卤石数据库中主要元素氧化物、镍、铜和 S 的含量。模拟的橄榄石中的镍含量与来自 Kevitsa 和 Sakatti 的文献数据相一致,从而为识别 CLGB 科马蒂岩和相关侵入岩中的贫镍橄榄石提供了基线。我们的研究表明,科马蒂岩母体熔体的部分结晶可形成富镍或富铜的硫化物熔体,这取决于母体熔体的初始镍和硒含量。
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From the mantle source to the crustal sink: magmatic differentiation and sulfide saturation of the Paleoproterozoic komatiites of the Central Lapland Greenstone Belt, Finland

Paleoproterozoic (2.05 Ga) komatiites are widespread in the Central Lapland Greenstone Belt (CLGB), northern Finland. Close association with sulfur (S)-rich country rocks and spatiotemporal connection with the Cu-Ni(-PGE) deposits of Kevitsa and Sakatti make these komatiites interesting targets for sulfide deposit exploration. We provide whole-rock geochemical data from Sattasvaara komatiites and combine it with literature data to form a geochemical database for the CLGB komatiites. We construct a model for the komatiites from adiabatic melting of the mantle source to fractional crystallization at crustal conditions. Using MELTS, we calculate three parental melts (MgO = 20.6–25.7 wt%) in equilibrium with Fo92, Fo93, and Fo94 olivine for the CLGB komatiites. Based on REEBOX PRO simulations, these parental melts can form from a single mantle source by different pressures and degrees of melting when the potential temperature is 1575–1700 °C. We calculate ranges of S contents for the parental melts based on the different mantle melting conditions and degrees of melting. We use Magma Chamber Simulator to fractionally crystallize the parental melt at crustal conditions. These simulations reproduce the major element oxide, Ni, Cu, and S contents from our komatiite database. Simulated Ni contents in olivine are compatible with literature data from Kevitsa and Sakatti, hence providing a baseline to identify Ni-depleted olivine in CLGB komatiites and related intrusive rocks. We show that fractional crystallization of the komatiitic parental melt can form either Ni-rich or Cu-rich sulfide melt, depending on the initial Ni and S content of the parental melt.

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来源期刊
Contributions to Mineralogy and Petrology
Contributions to Mineralogy and Petrology 地学-地球化学与地球物理
CiteScore
6.50
自引率
5.70%
发文量
94
审稿时长
1.7 months
期刊介绍: Contributions to Mineralogy and Petrology is an international journal that accepts high quality research papers in the fields of igneous and metamorphic petrology, geochemistry and mineralogy. Topics of interest include: major element, trace element and isotope geochemistry, geochronology, experimental petrology, igneous and metamorphic petrology, mineralogy, major and trace element mineral chemistry and thermodynamic modeling of petrologic and geochemical processes.
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