{"title":"飞蛾眼状微纳结构光学抗反射涂层的制备与研究","authors":"Lielun Zhao, Yawen Guo, Tiantai Kang, Yan Jiang, Haobin Zhang, Hongwen Zhang","doi":"10.1134/s1560090424600517","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Copolymers were synthesized from acrylate monomers and ladder-shaped polysilsesquioxanes (LPSQ) using free radical polymerization, and the copolymers were coated on polyethylene terephthalate (PET) films by the lift-off impregnation method. The nanosized SiO<sub>2</sub> sols with different particle sizes were prepared by sol-gel method, and then the nanosized SiO<sub>2</sub> sols were coated on the surface modified PET film to construct a moth-eye-like anti-reflection coating by using the layer-by-layer self-assembly method. The structure and composition of LPSQ and modified acrylic resin copolymer were characterized by infrared spectroscopy and X-ray diffraction, and the transmittance/haze tester and UV spectrophotometer were used to test the performance of the anti-reflection coating, which could reach 94.0% compared with 89.2% of the matrix pure PET film. Thermogravimetric analysis showed that the thermal decomposition temperature of the LPSQ-modified copolymer material was higher than that of the pure acrylate copolymer.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and Study of Moth-Eye-Like Micro-Nano Structure Optical Anti-Reflection Coating\",\"authors\":\"Lielun Zhao, Yawen Guo, Tiantai Kang, Yan Jiang, Haobin Zhang, Hongwen Zhang\",\"doi\":\"10.1134/s1560090424600517\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>Copolymers were synthesized from acrylate monomers and ladder-shaped polysilsesquioxanes (LPSQ) using free radical polymerization, and the copolymers were coated on polyethylene terephthalate (PET) films by the lift-off impregnation method. The nanosized SiO<sub>2</sub> sols with different particle sizes were prepared by sol-gel method, and then the nanosized SiO<sub>2</sub> sols were coated on the surface modified PET film to construct a moth-eye-like anti-reflection coating by using the layer-by-layer self-assembly method. The structure and composition of LPSQ and modified acrylic resin copolymer were characterized by infrared spectroscopy and X-ray diffraction, and the transmittance/haze tester and UV spectrophotometer were used to test the performance of the anti-reflection coating, which could reach 94.0% compared with 89.2% of the matrix pure PET film. Thermogravimetric analysis showed that the thermal decomposition temperature of the LPSQ-modified copolymer material was higher than that of the pure acrylate copolymer.</p>\",\"PeriodicalId\":739,\"journal\":{\"name\":\"Polymer Science, Series B\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2024-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Science, Series B\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1134/s1560090424600517\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1134/s1560090424600517","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
摘要
摘要 以丙烯酸酯单体和梯形聚硅氧烷（LPSQ）为原料，采用自由基聚合法合成共聚物。采用溶胶-凝胶法制备了不同粒径的纳米二氧化硅溶胶，然后利用逐层自组装法将纳米二氧化硅溶胶涂覆在表面改性的 PET 薄膜上，构建了蛾眼状抗反射涂层。利用红外光谱和 X 射线衍射对 LPSQ 和改性丙烯酸树脂共聚物的结构和组成进行了表征，并使用透射率/霞光测试仪和紫外分光光度计测试了抗反射涂层的性能。热重分析表明，LPSQ 改性共聚物材料的热分解温度高于纯丙烯酸酯共聚物。
Preparation and Study of Moth-Eye-Like Micro-Nano Structure Optical Anti-Reflection Coating
Abstract
Copolymers were synthesized from acrylate monomers and ladder-shaped polysilsesquioxanes (LPSQ) using free radical polymerization, and the copolymers were coated on polyethylene terephthalate (PET) films by the lift-off impregnation method. The nanosized SiO2 sols with different particle sizes were prepared by sol-gel method, and then the nanosized SiO2 sols were coated on the surface modified PET film to construct a moth-eye-like anti-reflection coating by using the layer-by-layer self-assembly method. The structure and composition of LPSQ and modified acrylic resin copolymer were characterized by infrared spectroscopy and X-ray diffraction, and the transmittance/haze tester and UV spectrophotometer were used to test the performance of the anti-reflection coating, which could reach 94.0% compared with 89.2% of the matrix pure PET film. Thermogravimetric analysis showed that the thermal decomposition temperature of the LPSQ-modified copolymer material was higher than that of the pure acrylate copolymer.
期刊介绍：
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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