{"title":"液态胺封端氟橡胶的制备、固化和性能","authors":"Gaofei Yuan, Mingyi Liao, Yunfei Chang","doi":"10.1134/S1560090424600372","DOIUrl":null,"url":null,"abstract":"<p>A two-step nucleophilic substitution mechanism was used and described to prepare liquid amine-terminated fluoroelastomers (LTAFs) by using liquid hydroxy-terminated fluoroelastomers (LTHFs) as raw materials, benzenesulfonyl chloride as an activator, and hexanediamine as an amine source. A reaction time of 24 h at 18°C and a molar ratio of groups –NH<sub>2</sub>/–OH = 6.00 is an optimal condition for obtaining LTAFs with a yield of amino groups of 51%. The resulting LTAFs has a higher viscosity and lower thermal stability than LTHFs, while the molecular weight and distribution, as well as the glass transition temperature, remain essentially similar. Aziridine cured LTAFs has the best comprehensive mechanical properties and excellent chemical solvent resistance.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"66 1","pages":"19 - 31"},"PeriodicalIF":1.0000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation, Curing and Properties of Liquid Amine-Terminated Fluoroelastomers\",\"authors\":\"Gaofei Yuan, Mingyi Liao, Yunfei Chang\",\"doi\":\"10.1134/S1560090424600372\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A two-step nucleophilic substitution mechanism was used and described to prepare liquid amine-terminated fluoroelastomers (LTAFs) by using liquid hydroxy-terminated fluoroelastomers (LTHFs) as raw materials, benzenesulfonyl chloride as an activator, and hexanediamine as an amine source. A reaction time of 24 h at 18°C and a molar ratio of groups –NH<sub>2</sub>/–OH = 6.00 is an optimal condition for obtaining LTAFs with a yield of amino groups of 51%. The resulting LTAFs has a higher viscosity and lower thermal stability than LTHFs, while the molecular weight and distribution, as well as the glass transition temperature, remain essentially similar. Aziridine cured LTAFs has the best comprehensive mechanical properties and excellent chemical solvent resistance.</p>\",\"PeriodicalId\":739,\"journal\":{\"name\":\"Polymer Science, Series B\",\"volume\":\"66 1\",\"pages\":\"19 - 31\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2024-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Science, Series B\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1560090424600372\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1560090424600372","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Preparation, Curing and Properties of Liquid Amine-Terminated Fluoroelastomers
A two-step nucleophilic substitution mechanism was used and described to prepare liquid amine-terminated fluoroelastomers (LTAFs) by using liquid hydroxy-terminated fluoroelastomers (LTHFs) as raw materials, benzenesulfonyl chloride as an activator, and hexanediamine as an amine source. A reaction time of 24 h at 18°C and a molar ratio of groups –NH2/–OH = 6.00 is an optimal condition for obtaining LTAFs with a yield of amino groups of 51%. The resulting LTAFs has a higher viscosity and lower thermal stability than LTHFs, while the molecular weight and distribution, as well as the glass transition temperature, remain essentially similar. Aziridine cured LTAFs has the best comprehensive mechanical properties and excellent chemical solvent resistance.
期刊介绍：
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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