二氧化钛纳米粒子对提高工业应用有机聚合物材料性能活性的影响

IF 1.8 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY ECS Journal of Solid State Science and Technology Pub Date : 2024-06-07 DOI:10.1149/2162-8777/ad522e
B. M. Alotaibi, Haifa A. Alyousef, A. Atta, S. A. Rizk, Abdelfattah T. Elgendy
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The conductivity improved from 5.8 × 10<sup>−8 </sup>S.cm<sup>−1</sup> for MC to 3.8 × 10<sup>−6 </sup>S.cm<sup>−1</sup> for the composite MC/TiO<sub>2</sub>, and the dielectric constant <inline-formula>\n<tex-math>\n<?CDATA ${\\varepsilon }^{{\\prime} }$?>\n</tex-math>\n<mml:math overflow=\"scroll\"><mml:msup><mml:mrow><mml:mi>ε</mml:mi></mml:mrow><mml:mrow><mml:mo accent=\"true\">′</mml:mo></mml:mrow></mml:msup></mml:math>\n<inline-graphic xlink:href=\"jssad522eieqn1.gif\" xlink:type=\"simple\"></inline-graphic>\n</inline-formula> has risen from 87 for MC to 179 for the composite MC/TiO<sub>2</sub>. 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引用次数: 0

摘要

研究人员合成了由二氧化钛纳米粒子(TiO2NPs)和有机聚合物甲基纤维素(MC)组成的新型复合膜(MC/TiO2),并将其应用于光催化和工业领域。EDX 技术成功验证了 MC/TiO2 纳米复合材料薄膜的制备,证明了 TiO2 在 MC 中的均匀分布。此外,在 20 Hz 至 5.5 MHz 频率范围内,还测定了 MC 的介电性能与 TiO2 浓度的函数关系。电导率从 MC 的 5.8 × 10-8 S.cm-1 提高到 MC/TiO2 复合材料的 3.8 × 10-6 S.cm-1 ,介电常数 ε′ 从 MC 的 87 上升到 MC/TiO2 复合材料的 179。此外,能量密度从 MC 的 3.86 × 10-4 J m-3 增加到 MC/TiO2 的 7.94 × 10-4 J m-3,弛豫时间 τr 从 11.5 × 10-5 秒下降到 2.58 × 10-5。总之,这些数据表明 MC/TiO2 的介电特性得到了改变,可用于废水处理和储能装置等不同应用领域。
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Influence of TiO2 Nanoparticles on Enhancing the Properties Activity of Organic Polymeric Materials for Industrial Applications
Novel composite (MC/TiO2) films consisting of titanium dioxide nanoparticles (TiO2NPs) and organic polymer methylcellulose (MC), were synthesized for applied in photocatalysis and industrial sectors. The preparation of the nanocomposites MC/TiO2 films were verified successfully by EDX technique, which demonstrated the uniform distribution of TiO2 in the MC. Moreover, in frequency of 20 Hz to 5.5 MHz, the dielectric properties of MC as a function of TiO2 concentration were determined. The conductivity improved from 5.8 × 10−8 S.cm−1 for MC to 3.8 × 10−6 S.cm−1 for the composite MC/TiO2, and the dielectric constant ε has risen from 87 for MC to 179 for the composite MC/TiO2. In addition, the energy density increases from 3.86 × 10−4 J m−3 for MC to 7.94 × 10−4 J m−3 for MC/TiO2, and the relaxation time τr dropped from 11.5 × 10−5 sec to 2.58 × 10−5. In summary, the data investigated that the dielectric characteristics of MC/TiO2 were modified for usage in different applications as wastewater treatment and energy storage devices.
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来源期刊
ECS Journal of Solid State Science and Technology
ECS Journal of Solid State Science and Technology MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
CiteScore
4.50
自引率
13.60%
发文量
455
期刊介绍: The ECS Journal of Solid State Science and Technology (JSS) was launched in 2012, and publishes outstanding research covering fundamental and applied areas of solid state science and technology, including experimental and theoretical aspects of the chemistry and physics of materials and devices. JSS has five topical interest areas: carbon nanostructures and devices dielectric science and materials electronic materials and processing electronic and photonic devices and systems luminescence and display materials, devices and processing.
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