Huijing Chen, Bo Peng, Ping Zhang, Ying Yang, Xue Hu
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引用次数: 0
摘要
纳米铜簇(Cu NCs)作为一种新型荧光材料经常被用于检测金属离子,但大多数都是基于 "关闭 "模式。本文基于 Cu NCs@MIL-101 复合材料,开发了一种用于检测 Cr(Ⅵ)的 "开启 "模式荧光传感平台。Cu NCs@MIL-101 由 Cu NCs 和 MIL-101(Cr)简单混合合成,其中 Cu NCs 均匀分布在 MIL-101(Cr)中。值得注意的是,由于 MIL-101 的内部过滤效应(IFE),Cu NCs@MIL-101 的荧光强度明显减弱。当引入铬(Ⅵ)时,Cu NCs@MIL-101 的荧光将通过铬(Ⅵ)与 Cu NCs 的客体交换过程恢复,从而克服 Cu NCs@MIL-101 的内滤效应。在此基础上,成功构建了一种用于定量检测铬(Ⅵ)的 "开启式 "荧光探针,其线性范围分别为 0.05-1 μM 和 1-20 μM,检测限低至 0.05 μM。该荧光探针具有良好的选择性和抗干扰能力,已成功应用于实际水样中铬(Ⅵ)的检测,结果令人满意。该研究为 Cu NCs 的分析应用提供了一种新方法。
A “turn-on” fluorescence sensing for sensitively detecting Cr(Ⅵ) via a guest exchange process in Cu NCs@MIL-101 composites
Copper nanoclusters (Cu NCs) as a new fluorescent material are often used for determining metal ions, but most of them are based on the “turn-off” model. Here, a “turn-on” model of fluorescence sensing platform for the detection of Cr(Ⅵ) have been developed based on Cu NCs@MIL-101 composites. The Cu NCs@MIL-101 were synthesized by a simple mixture of the Cu NCs and MIL-101(Cr), in which the Cu NCs were uniformly distributed in MIL-101(Cr). Notably, the fluorescence intensity of Cu NCs@MIL-101 is significantly weakened due to the internal filtration effect (IFE) of MIL-101. When Cr(Ⅵ) is introduced, the fluorescence of Cu NCs@MIL-101 will be recovered by guest exchange process of Cr(Ⅵ) and the Cu NCs, which will overcome the IFE of Cu NCs@MIL-101. Based on this, a “turn-on” fluorescence probe was successfully constructed for the quantitative detection of Cr(Ⅵ) with two linear ranges of 0.05-1 μM and 1-20 μM, and a low detection limit of 0.05 μM. The proposed fluorescence probe possesses excellent selectivity and anti-interference ability, and has been successfully applied in the detection of Cr(Ⅵ) in real water samples with satisfactory results. This study provides a new approach for the analytical application of Cu NCs.