{"title":"设计和优化作为先进钾离子存储阳极的碳材料","authors":"Xiang Liu, Jian-Hua Chu, Zi-Xian Wang, Shao-Wei Hu, Zi-Yi Cheng, Ke-Ning Liu, Chao-Jie Zhang, Li-Qiang Zhang, Li-Dong Xing, Wei Wang","doi":"10.1007/s12598-024-02843-1","DOIUrl":null,"url":null,"abstract":"<p>With the swift advancement of renewable energy and escalating demands for energy storage, potassium-ion batteries (PIBs) are increasingly recognized as a potent energy storage technology. Various carbon anode materials have been utilized for PIBs anodes owing to their superior K<sup>+</sup> storage capacity, outstanding cycling performance, elevated capacity, and cost-effectiveness. Therefore, it is imperative to explore and improve carbon anode materials. This review meticulously encapsulates the recent scholarly advancements in carbon anode materials for PIBs. It elucidates the operational mechanisms of carbon anode for PIBs, provides a synopsis of diverse carbon materials, and deliberates on the prevalent challenges, including cycling stability and potassium-ion diffusion rates. Although soft and hard carbon augmented potassium-ion capacities, the expansive surface areas coupled with the large ionic radius of K<sup>+</sup> pose substantial challenges to their structural design and optimization. Consequently, this review outlines strategic approaches to the design of carbon materials for excellent potassium storage performance, including the expansion of interlayer spacing, modification of morphology, heteroatom doping, structural defect regulation, incorporation of porous structures, and development of carbon–carbon composites. Finally, the challenges and prospective solutions of carbon anode materials for PIBs with superior energy density and cycling stability were proposed, providing a reasonable guidance for regulation design of carbon materials.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":null,"pages":null},"PeriodicalIF":9.6000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Design and optimization of carbon materials as anodes for advanced potassium-ion storage\",\"authors\":\"Xiang Liu, Jian-Hua Chu, Zi-Xian Wang, Shao-Wei Hu, Zi-Yi Cheng, Ke-Ning Liu, Chao-Jie Zhang, Li-Qiang Zhang, Li-Dong Xing, Wei Wang\",\"doi\":\"10.1007/s12598-024-02843-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>With the swift advancement of renewable energy and escalating demands for energy storage, potassium-ion batteries (PIBs) are increasingly recognized as a potent energy storage technology. Various carbon anode materials have been utilized for PIBs anodes owing to their superior K<sup>+</sup> storage capacity, outstanding cycling performance, elevated capacity, and cost-effectiveness. Therefore, it is imperative to explore and improve carbon anode materials. This review meticulously encapsulates the recent scholarly advancements in carbon anode materials for PIBs. It elucidates the operational mechanisms of carbon anode for PIBs, provides a synopsis of diverse carbon materials, and deliberates on the prevalent challenges, including cycling stability and potassium-ion diffusion rates. Although soft and hard carbon augmented potassium-ion capacities, the expansive surface areas coupled with the large ionic radius of K<sup>+</sup> pose substantial challenges to their structural design and optimization. Consequently, this review outlines strategic approaches to the design of carbon materials for excellent potassium storage performance, including the expansion of interlayer spacing, modification of morphology, heteroatom doping, structural defect regulation, incorporation of porous structures, and development of carbon–carbon composites. Finally, the challenges and prospective solutions of carbon anode materials for PIBs with superior energy density and cycling stability were proposed, providing a reasonable guidance for regulation design of carbon materials.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical abstract</h3>\",\"PeriodicalId\":749,\"journal\":{\"name\":\"Rare Metals\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":9.6000,\"publicationDate\":\"2024-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Rare Metals\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1007/s12598-024-02843-1\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Rare Metals","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1007/s12598-024-02843-1","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Design and optimization of carbon materials as anodes for advanced potassium-ion storage
With the swift advancement of renewable energy and escalating demands for energy storage, potassium-ion batteries (PIBs) are increasingly recognized as a potent energy storage technology. Various carbon anode materials have been utilized for PIBs anodes owing to their superior K+ storage capacity, outstanding cycling performance, elevated capacity, and cost-effectiveness. Therefore, it is imperative to explore and improve carbon anode materials. This review meticulously encapsulates the recent scholarly advancements in carbon anode materials for PIBs. It elucidates the operational mechanisms of carbon anode for PIBs, provides a synopsis of diverse carbon materials, and deliberates on the prevalent challenges, including cycling stability and potassium-ion diffusion rates. Although soft and hard carbon augmented potassium-ion capacities, the expansive surface areas coupled with the large ionic radius of K+ pose substantial challenges to their structural design and optimization. Consequently, this review outlines strategic approaches to the design of carbon materials for excellent potassium storage performance, including the expansion of interlayer spacing, modification of morphology, heteroatom doping, structural defect regulation, incorporation of porous structures, and development of carbon–carbon composites. Finally, the challenges and prospective solutions of carbon anode materials for PIBs with superior energy density and cycling stability were proposed, providing a reasonable guidance for regulation design of carbon materials.
期刊介绍:
Rare Metals is a monthly peer-reviewed journal published by the Nonferrous Metals Society of China. It serves as a platform for engineers and scientists to communicate and disseminate original research articles in the field of rare metals. The journal focuses on a wide range of topics including metallurgy, processing, and determination of rare metals. Additionally, it showcases the application of rare metals in advanced materials such as superconductors, semiconductors, composites, and ceramics.