改性二氧化铈在光催化空气污染净化中的应用

IF 9.6 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Rare Metals Pub Date : 2024-06-24 DOI:10.1007/s12598-024-02746-1
Cheng-Zhang Zhu, Qi-Hang Tian, Bing-Han Wang, Mu-Tao Xu, Qi-Jie Jin, Zi-Ye Zhang, Shu-Kun Le, Yang Wu, Yue-Chang Wei, Hai-Tao Xu
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引用次数: 0

摘要

二氧化铈(CeO2)是一种重要的稀土氧化物,具有丰富的氧缺陷、特异的 4f15d1 轨道以及 Ce4+/Ce3+ 可逆对中卓越的氧储存释放能力等优点,已作为一种活性光催化材料在空气污染修复领域得到广泛研究。为了提高 CeO2 的光催化效率,近年来人们采用了许多改性策略来拓宽光吸收范围和降低电子-空穴对的重组率。本综述总结了改性 CeO2 催化剂的制造方法,包括金属或非金属掺杂、异质结构构建和氧空位制造,以深入探讨这些先进技术如何提高光催化活性。此外,本研究还详细讨论了改性 CeO2 在空气污染控制领域的应用,包括氮氧化物去除、挥发性有机化合物消除和二氧化碳净化。最后,还指出了未来在改性 CeO2 方面的潜在发展和进一步研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Application of modified cerium dioxide for photocatalytic air pollution purification

Cerium dioxide (CeO2) is a significant rare earth oxide with the merits of rich oxygen defects, specific 4f15d1 orbitals, and superior oxygen storage-release capacity in Ce4+/Ce3+ reversibility pairs, and has been widely investigated as an active photocatalytic material for air pollution remediation. To enhance the photocatalytic efficiency of CeO2, recent developments of numerous modification strategies have been employed to broaden the light absorption range and reduce the recombination rate of electron–hole pairs. This review summarizes the fabrication of modified CeO2 catalysts, including metal or nonmetal doping, heterostructure construction and oxygen vacancy manufacturing, to provide insight into how those advanced techniques improve the photocatalytic activity. Moreover, this work provides a detailed discussion on the usage of modified CeO2 in the fields of air pollution control, including nitrogen oxides removal, volatile organic compounds elimination and the purification of carbon dioxide. Finally, the potential future development and further research on the modification of CeO2 has been identified.

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来源期刊
Rare Metals
Rare Metals 工程技术-材料科学:综合
CiteScore
12.10
自引率
12.50%
发文量
2919
审稿时长
2.7 months
期刊介绍: Rare Metals is a monthly peer-reviewed journal published by the Nonferrous Metals Society of China. It serves as a platform for engineers and scientists to communicate and disseminate original research articles in the field of rare metals. The journal focuses on a wide range of topics including metallurgy, processing, and determination of rare metals. Additionally, it showcases the application of rare metals in advanced materials such as superconductors, semiconductors, composites, and ceramics.
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