{"title":"使用新型 Cu35Ni35Cr10Fe10Sn10 高熵合金填料进行金刚石钎焊","authors":"Haifeng Wei, Hui Zhang, Dong Xu, Weihuo Li, Qiang Hu, Sheng Guo","doi":"10.1111/jace.19984","DOIUrl":null,"url":null,"abstract":"<p>A novel Cu<sub>35</sub>Ni<sub>35</sub>Cr<sub>10</sub>Fe<sub>10</sub>Sn<sub>10</sub> high-entropy alloy (HEA) filler with a relatively low melting point (935°C) was designed for brazing diamonds, and its technical advantages over conventional NiCr-based fillers, that is, favorable wettability, high bonding strength, low thermal damage, and high mechanical performance, were convincingly demonstrated. The newly developed HEA filler had a contact angle of only 11° on the graphite (energetically close to diamond) surface and it could braze diamonds at 1000°C, much lower than the brazing temperature of conventional NiCr-based fillers. Consequently, the brazed diamond exhibited greatly decreased surface thermal damage, higher fracture strength, and better wear performance. The solidified microstructure of the HEA filler contained three solid solution phases, that is, FeCrNi-rich, CuNi-rich, and CuSnNi-rich phases that were formed through the liquid phase separation process, plus a minor phase of nanosized FeCr-rich precipitates. The reaction products at the HEA filler/diamond interface were simply an inner Cr<sub>3</sub>C<sub>2</sub> layer and an outer Cr<sub>7</sub>C<sub>3</sub> layer, without other complex brittle compounds that are commonly seen in NiCr-based fillers after diamond brazing. Apparently, the HEA filler reacted more sufficiently with diamonds, which contributed to improve the bonding strength and wear resistance of the brazed diamond. This work provided a new application scenario for HEAs as promising filler materials for brazing diamonds.</p>","PeriodicalId":200,"journal":{"name":"Journal of the American Ceramic Society","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2024-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Diamonds brazing with a novel Cu35Ni35Cr10Fe10Sn10 high-entropy alloy filler\",\"authors\":\"Haifeng Wei, Hui Zhang, Dong Xu, Weihuo Li, Qiang Hu, Sheng Guo\",\"doi\":\"10.1111/jace.19984\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A novel Cu<sub>35</sub>Ni<sub>35</sub>Cr<sub>10</sub>Fe<sub>10</sub>Sn<sub>10</sub> high-entropy alloy (HEA) filler with a relatively low melting point (935°C) was designed for brazing diamonds, and its technical advantages over conventional NiCr-based fillers, that is, favorable wettability, high bonding strength, low thermal damage, and high mechanical performance, were convincingly demonstrated. The newly developed HEA filler had a contact angle of only 11° on the graphite (energetically close to diamond) surface and it could braze diamonds at 1000°C, much lower than the brazing temperature of conventional NiCr-based fillers. Consequently, the brazed diamond exhibited greatly decreased surface thermal damage, higher fracture strength, and better wear performance. The solidified microstructure of the HEA filler contained three solid solution phases, that is, FeCrNi-rich, CuNi-rich, and CuSnNi-rich phases that were formed through the liquid phase separation process, plus a minor phase of nanosized FeCr-rich precipitates. The reaction products at the HEA filler/diamond interface were simply an inner Cr<sub>3</sub>C<sub>2</sub> layer and an outer Cr<sub>7</sub>C<sub>3</sub> layer, without other complex brittle compounds that are commonly seen in NiCr-based fillers after diamond brazing. Apparently, the HEA filler reacted more sufficiently with diamonds, which contributed to improve the bonding strength and wear resistance of the brazed diamond. This work provided a new application scenario for HEAs as promising filler materials for brazing diamonds.</p>\",\"PeriodicalId\":200,\"journal\":{\"name\":\"Journal of the American Ceramic Society\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-06-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the American Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1111/jace.19984\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the American Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/jace.19984","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Diamonds brazing with a novel Cu35Ni35Cr10Fe10Sn10 high-entropy alloy filler
A novel Cu35Ni35Cr10Fe10Sn10 high-entropy alloy (HEA) filler with a relatively low melting point (935°C) was designed for brazing diamonds, and its technical advantages over conventional NiCr-based fillers, that is, favorable wettability, high bonding strength, low thermal damage, and high mechanical performance, were convincingly demonstrated. The newly developed HEA filler had a contact angle of only 11° on the graphite (energetically close to diamond) surface and it could braze diamonds at 1000°C, much lower than the brazing temperature of conventional NiCr-based fillers. Consequently, the brazed diamond exhibited greatly decreased surface thermal damage, higher fracture strength, and better wear performance. The solidified microstructure of the HEA filler contained three solid solution phases, that is, FeCrNi-rich, CuNi-rich, and CuSnNi-rich phases that were formed through the liquid phase separation process, plus a minor phase of nanosized FeCr-rich precipitates. The reaction products at the HEA filler/diamond interface were simply an inner Cr3C2 layer and an outer Cr7C3 layer, without other complex brittle compounds that are commonly seen in NiCr-based fillers after diamond brazing. Apparently, the HEA filler reacted more sufficiently with diamonds, which contributed to improve the bonding strength and wear resistance of the brazed diamond. This work provided a new application scenario for HEAs as promising filler materials for brazing diamonds.
期刊介绍:
The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials.
Papers on fundamental ceramic and glass science are welcome including those in the following areas:
Enabling materials for grand challenges[...]
Materials design, selection, synthesis and processing methods[...]
Characterization of compositions, structures, defects, and properties along with new methods [...]
Mechanisms, Theory, Modeling, and Simulation[...]
JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.