{"title":"具有多种构型的柔性多孔配位聚合物，可识别访客并具有可切换的二氧化碳吸附特性","authors":"Ping Wang, Ken-ichi Otake, Shotaro Hiraide, Yoshiki Kubota, Shogo Kawaguchi, Susumu Kitagawa","doi":"10.1093/chemle/upae128","DOIUrl":null,"url":null,"abstract":"Realizing multiple metastable configurations in a single porous coordination polymer (PCP) has long been pursued to achieve switchable functionality. In this study, we reported multiple configurations in one PCP material via the design of the adjustable intraframework π-π stacking moieties. We demonstrated that the PCP can accommodate three different open pore phases depending on the type of solvent. Furthermore, this PCP exhibits three distinct closed pore phases depending on the activation approaches, demonstrating different CO2 sorption properties.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Flexible Porous Coordination Polymer with Multiple Configurations for Guest Recognition and Switchable CO2 Sorption Properties\",\"authors\":\"Ping Wang, Ken-ichi Otake, Shotaro Hiraide, Yoshiki Kubota, Shogo Kawaguchi, Susumu Kitagawa\",\"doi\":\"10.1093/chemle/upae128\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Realizing multiple metastable configurations in a single porous coordination polymer (PCP) has long been pursued to achieve switchable functionality. In this study, we reported multiple configurations in one PCP material via the design of the adjustable intraframework π-π stacking moieties. We demonstrated that the PCP can accommodate three different open pore phases depending on the type of solvent. Furthermore, this PCP exhibits three distinct closed pore phases depending on the activation approaches, demonstrating different CO2 sorption properties.\",\"PeriodicalId\":9862,\"journal\":{\"name\":\"Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1093/chemle/upae128\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upae128","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Flexible Porous Coordination Polymer with Multiple Configurations for Guest Recognition and Switchable CO2 Sorption Properties
Realizing multiple metastable configurations in a single porous coordination polymer (PCP) has long been pursued to achieve switchable functionality. In this study, we reported multiple configurations in one PCP material via the design of the adjustable intraframework π-π stacking moieties. We demonstrated that the PCP can accommodate three different open pore phases depending on the type of solvent. Furthermore, this PCP exhibits three distinct closed pore phases depending on the activation approaches, demonstrating different CO2 sorption properties.
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