基于煤基碳/二氧化硅纳米杂化材料的高选择性丙酮传感器

IF 3.4 3区 综合性期刊 Q2 CHEMISTRY, ANALYTICAL Sensors Pub Date : 2024-07-03 DOI:10.3390/s24134320
Min Zhang, Yi Han, Ting Liu, Hongguang Jia
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引用次数: 0

摘要

高温是气体传感器开发过程中的一个关键制约因素。因此,研究在室温下工作的气体传感器具有重要的现实意义。本研究采用简单的一步气相沉积和烧结法合成了煤基多孔碳(C-700)和煤基 C/MoO2 纳米杂化材料,并研究了它们的气体传感性能。测试了几种挥发性有机化合物气体(苯酚、乙酸乙酯、乙醇、丙酮、三乙胺和甲苯)和 95% 相对湿度的高湿度环境下的气敏性能。结果表明,在 450 °C 下烧结的 C/MoO2-450 样品在室温下对丙酮具有极佳的特定选择性,响应值为 4153.09%,响应/恢复时间分别为 10.8 秒和 2.9 秒。此外,C/MoO2-450 样品还具有良好的重复性和长期稳定性。研究人员还对合成材料的传感机理进行了探讨。优异的气体传感性能可归因于多孔碳和 MoO2 纳米粒子之间的协同效应。鉴于提高煤炭高科技和高附加值利用的重要性,本研究为利用煤基碳材料在室温下检测挥发性有机化合物提供了一种可行的方法。
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A Highly Selective Acetone Sensor Based on Coal-Based Carbon/MoO2 Nanohybrid Material
High temperature represents a critical constraint in the development of gas sensors. Therefore, investigating gas sensors operating at room temperature holds significant practical importance. In this study, coal-based porous carbon (C-700) and coal-based C/MoO2 nanohybrid materials were synthesized using a simple one-step vapor deposition and sintering method, and their gas-sensing performance was investigated. The gas-sensing performance for several VOC gases (phenol, ethyl acetate, ethanol, acetone, triethylamine, and toluene) and a 95% RH high-humidity environment were tested. The results indicated that the C/MoO2-450 sample sintered at 450 °C exhibited excellent specific selectivity towards acetone at room temperature, with a response value of 4153.09% and response/recovery times of 10.8 s and 2.9 s, respectively. Furthermore, the C/MoO2-450 sample also demonstrated good repeatability and long-term stability. The sensing mechanism of the synthesized materials was also explored. The superior gas-sensing performance can be attributed to the synergistic effect between the porous carbon and MoO2 nanoparticles. Given the importance of enhancing the high-tech and high-value-added utilization of coal, this study provides a viable approach for utilizing coal-based carbon materials in detecting volatile organic compounds at room temperature.
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来源期刊
Sensors
Sensors 工程技术-电化学
CiteScore
7.30
自引率
12.80%
发文量
8430
审稿时长
1.7 months
期刊介绍: Sensors (ISSN 1424-8220) provides an advanced forum for the science and technology of sensors and biosensors. It publishes reviews (including comprehensive reviews on the complete sensors products), regular research papers and short notes. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. There is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.
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