Guoying Shi, Hongwei Fan, Weixuan Wang, Chengyi Hou, Qinghong Zhang, Yaogang Li, Hong Xiao, Guoliang Dai, Kerui Li, Hongzhi Wang
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Carbon nanotube-grid infrared transparent electrodes for flexible electrochromic devices with visible to mid-infrared dual-band modulation
Flexible mid-infrared electrochromic devices (MIR-ECDs) have attracted wide attention due to the growing demands for thermal camouflage and body comfort. However, the normal conductive films (e.g., indium tin oxide/polyethylene terephthalate (ITO/PET) films) are unsuitable for MIR-ECDs due to low infrared transmittance. Herein, the infrared transparent carbon nanotube (CNT) grid films were prepared by designing the grid structure. The infrared transmittance of CNT grid film could reach 72 %; meanwhile, the visible transmittance could reach 75 %. The CNTs exhibited infrared modulation under different voltages due to the doping/de-doping of ions in electrolytes into the CNT network. The flexible electrochromic devices with visible to mid-infrared dual-band modulation were prepared by using CNT grid film as the electrode and poly (3,4 ethylenedioxythiophene):poly (styrene sulfonate) (PEDOT:PSS) as the electrochromic layer, which could realize the infrared synergistic modulation of PEDOT:PSS and CNT grid in the mid-infrared range and reversible color changes between light blue and dark blue in the visible range, showing promising applications in adaptive camouflage and thermal management.
期刊介绍:
Materials Today Chemistry is a multi-disciplinary journal dedicated to all facets of materials chemistry.
This field represents one of the fastest-growing areas of science, involving the application of chemistry-based techniques to the study of materials. It encompasses materials synthesis and behavior, as well as the intricate relationships between material structure and properties at the atomic and molecular scale. Materials Today Chemistry serves as a high-impact platform for discussing research that propels the field forward through groundbreaking discoveries and innovative techniques.