Li Xu, Chenfei Zhu, Xiaogang Duan, Lei Bao, Guanglin Wang, Wei Fu
{"title":"基于从生物废弃物中提取的荧光碳量子点的便携式智能手机平台,用于现场检测高锰酸盐","authors":"Li Xu, Chenfei Zhu, Xiaogang Duan, Lei Bao, Guanglin Wang, Wei Fu","doi":"10.1039/d4nj01987c","DOIUrl":null,"url":null,"abstract":"“Waste” is “wealth”: the transformation of biomass waste into high value-added substances holds significant environmental and economic importance. In our work, orange peel was effectively transformed into valuable fluorescent carbon quantum dots (CQDs) by solvothermal treatment. The resultant CQDs displayed favorable dispersion and a mean particle size of 3.14 ± 0.71 nm. Moreover, these CQDs exhibited a characteristic excitation-dependent fluorescence behavior, which can produce the maximum emission wavelength at 506 nm with excitation at 400 nm. Upon the introduction of permanganate (MnO<small><sub>4</sub></small><small><sup>−</sup></small>), the fluorescence intensity of CQDs diminished gradually caused by the inner filter effect (IFE) as well as the static quenching effect (SQE). The results revealed that the CQDs can serve as a fluorescent probe, which possessed high performance in terms of sensitivity for quantitative analysis of MnO<small><sub>4</sub></small><small><sup>−</sup></small>, boasting a low detection limit of 3.31 μM. Subsequently, the application of this fluorescent probe in actual water samples was further explored, resulting in a recovery rate between 98.18% and 101.69%, with relative standard deviations (RSDs) ranging from 1.85% to 2.68%, which was highly satisfactory. The portable paper-based sensor, fabricated by depositing CQDs onto filter paper, is capable of quantitatively and visually detecting MnO<small><sub>4</sub></small><small><sup>−</sup></small> in combination with a smartphone, thus providing a rapid on-site detection tool for MnO<small><sub>4</sub></small><small><sup>−</sup></small>. As far as we know, this study provides the inaugural account of a smartphone-based portable sensor for visual determination of MnO<small><sub>4</sub></small><small><sup>−</sup></small> by using biomass waste based CQDs, suggesting its immense potential for real-time monitoring applications.","PeriodicalId":95,"journal":{"name":"New Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A portable smartphone platform based on fluorescent carbon quantum dots derived from biowaste for on-site detection of permanganate\",\"authors\":\"Li Xu, Chenfei Zhu, Xiaogang Duan, Lei Bao, Guanglin Wang, Wei Fu\",\"doi\":\"10.1039/d4nj01987c\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"“Waste” is “wealth”: the transformation of biomass waste into high value-added substances holds significant environmental and economic importance. In our work, orange peel was effectively transformed into valuable fluorescent carbon quantum dots (CQDs) by solvothermal treatment. The resultant CQDs displayed favorable dispersion and a mean particle size of 3.14 ± 0.71 nm. Moreover, these CQDs exhibited a characteristic excitation-dependent fluorescence behavior, which can produce the maximum emission wavelength at 506 nm with excitation at 400 nm. Upon the introduction of permanganate (MnO<small><sub>4</sub></small><small><sup>−</sup></small>), the fluorescence intensity of CQDs diminished gradually caused by the inner filter effect (IFE) as well as the static quenching effect (SQE). The results revealed that the CQDs can serve as a fluorescent probe, which possessed high performance in terms of sensitivity for quantitative analysis of MnO<small><sub>4</sub></small><small><sup>−</sup></small>, boasting a low detection limit of 3.31 μM. Subsequently, the application of this fluorescent probe in actual water samples was further explored, resulting in a recovery rate between 98.18% and 101.69%, with relative standard deviations (RSDs) ranging from 1.85% to 2.68%, which was highly satisfactory. The portable paper-based sensor, fabricated by depositing CQDs onto filter paper, is capable of quantitatively and visually detecting MnO<small><sub>4</sub></small><small><sup>−</sup></small> in combination with a smartphone, thus providing a rapid on-site detection tool for MnO<small><sub>4</sub></small><small><sup>−</sup></small>. As far as we know, this study provides the inaugural account of a smartphone-based portable sensor for visual determination of MnO<small><sub>4</sub></small><small><sup>−</sup></small> by using biomass waste based CQDs, suggesting its immense potential for real-time monitoring applications.\",\"PeriodicalId\":95,\"journal\":{\"name\":\"New Journal of Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"New Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4nj01987c\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"New Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4nj01987c","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A portable smartphone platform based on fluorescent carbon quantum dots derived from biowaste for on-site detection of permanganate
“Waste” is “wealth”: the transformation of biomass waste into high value-added substances holds significant environmental and economic importance. In our work, orange peel was effectively transformed into valuable fluorescent carbon quantum dots (CQDs) by solvothermal treatment. The resultant CQDs displayed favorable dispersion and a mean particle size of 3.14 ± 0.71 nm. Moreover, these CQDs exhibited a characteristic excitation-dependent fluorescence behavior, which can produce the maximum emission wavelength at 506 nm with excitation at 400 nm. Upon the introduction of permanganate (MnO4−), the fluorescence intensity of CQDs diminished gradually caused by the inner filter effect (IFE) as well as the static quenching effect (SQE). The results revealed that the CQDs can serve as a fluorescent probe, which possessed high performance in terms of sensitivity for quantitative analysis of MnO4−, boasting a low detection limit of 3.31 μM. Subsequently, the application of this fluorescent probe in actual water samples was further explored, resulting in a recovery rate between 98.18% and 101.69%, with relative standard deviations (RSDs) ranging from 1.85% to 2.68%, which was highly satisfactory. The portable paper-based sensor, fabricated by depositing CQDs onto filter paper, is capable of quantitatively and visually detecting MnO4− in combination with a smartphone, thus providing a rapid on-site detection tool for MnO4−. As far as we know, this study provides the inaugural account of a smartphone-based portable sensor for visual determination of MnO4− by using biomass waste based CQDs, suggesting its immense potential for real-time monitoring applications.