制备具有更强可见光光催化活性的新型镍铁钛过氧化物复合材料

IF 1.6 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR Transition Metal Chemistry Pub Date : 2024-06-29 DOI:10.1007/s11243-024-00595-6
Byung-Geon Park
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引用次数: 0

摘要

本研究新制备了一种镍铁钛酸(NiFeTiO3)包晶石复合材料,并对其在可见光照射下的光催化活性进行了评估。该复合材料采用溶胶-凝胶法和溶胶-热法相结合的合成方法制备。研究了所制备的 NiFeTiO3 包晶石的物理化学和光学性质。本研究评估了新制备的 NiFeTiO3 包晶复合材料在可见光照射下的光催化活性。该复合材料采用溶胶-凝胶法和溶胶-热法相结合的方法合成。研究了所制备的 NiFeTiO3 包晶的物理化学和光学特性。具有 NiFeTiO3 结构的包晶复合材料对 800 纳米以上的可见光具有极佳的吸收能力。其带隙能约为 1.8 eV。在可见光照射下,对 NiFeTiO3 复合材料的光催化活性进行了评估。与 NiTiO3 相比,NiFeTiO3 具有更强的可见光吸收能力。它对亚甲蓝和甲醛具有优异的分解性能。此外,它在杀灭病原菌方面的光催化活性也远高于 NiTiO3 包晶。在利用太阳能进行水分离时,NiFeTiO3 催化剂通过光催化分解反应产生氢气。NiFeTiO3 复合材料对可见光的灵敏度高,因此被认为是一种光催化功能显著提高的过氧化物复合材料。
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Fabrication of a new nickel iron-titanate perovskite composite with enhanced visible light photocatalytic activity

In this study, a nickel iron-titanate (NiFeTiO3) perovskite composite was prepared newly and its photocatalytic activity was evaluated under visible light irradiation. The composite material was prepared by a synthetic method combining the sol–gel method and the solvothermal method. The physicochemical and optical properties of the prepared NiFeTiO3 perovskites were investigated. In this study, a newly prepared NiFeTiO3 perovskite composite was evaluated for its photocatalytic activity under visible light irradiation. The composite material was synthesized using a combination of the sol–gel method and the solvothermal method. The physicochemical and optical properties of the prepared NiFeTiO3 perovskites were investigated. The perovskite composites with the NiFeTiO3 structure had excellent absorption ability for visible light above 800 nm. Its bandgap energy was found to be approximately 1.8 eV. The photocatalytic activity of the NiFeTiO3 composite was evaluated under visible light irradiation. The NiFeTiO3 had superior visible light absorption ability compared to NiTiO3. It had excellent decomposition performance for methylene blue and formaldehyde. In addition, the photocatalytic activity for sterilizing pathogenic bacteria was much higher than that of NiTiO3 perovskite. In the water splitting by solar energy, the NiFeTiO3 catalysts produced hydrogen through a photocatalytic decomposition reaction. The NiFeTiO3 composite was considered a perovskite composite with significantly improved photocatalytic function due to its high sensitivity to visible light.

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来源期刊
Transition Metal Chemistry
Transition Metal Chemistry 化学-无机化学与核化学
CiteScore
3.60
自引率
0.00%
发文量
32
审稿时长
1.3 months
期刊介绍: Transition Metal Chemistry is an international journal designed to deal with all aspects of the subject embodied in the title: the preparation of transition metal-based molecular compounds of all kinds (including complexes of the Group 12 elements), their structural, physical, kinetic, catalytic and biological properties, their use in chemical synthesis as well as their application in the widest context, their role in naturally occurring systems etc. Manuscripts submitted to the journal should be of broad appeal to the readership and for this reason, papers which are confined to more specialised studies such as the measurement of solution phase equilibria or thermal decomposition studies, or papers which include extensive material on f-block elements, or papers dealing with non-molecular materials, will not normally be considered for publication. Work describing new ligands or coordination geometries must provide sufficient evidence for the confident assignment of structural formulae; this will usually take the form of one or more X-ray crystal structures.
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