{"title":"用于光化学和电化学固氮应用的平地材料:从实验室实验到大规模应用","authors":"Syed Asim Ali, Iqra Sadiq and Tokeer Ahmad","doi":"10.1039/D4SE00565A","DOIUrl":null,"url":null,"abstract":"<p >Rational design of materials in a catalytic system is the main determinant of the efficiency of sustainable energy sources. Significant efforts have focused on the study and development of flatland two-dimensional (2D) materials (MXenes, MBenes, transition metal dichalcogenides/phosphides (TMDs/TMPs), phosphorene, graphene derivatives) towards energy-driven aspirations in consideration of their superior physiochemical properties as compared to their non-layered counterpart materials, surpassing their transport properties and conductivity. Herein, we aim to provide a detailed account of where the flatland materials currently stand to achieve the goal of sustainability in light of their photochemical and electrochemical nitrogen fixation applications. As of now, numerous challenges have limited the expansion of 2D-material derived nitrogen fixation operations for scalable applications. Therefore, we summarized techno-economic analysis and future perspectives of nitrogen fixation applications in relation to their practical ammonia applicability. We have briefly summarized the functionality of flatland materials and classified them on the basis of their photochemical and electrochemical efficiencies.</p>","PeriodicalId":104,"journal":{"name":"Sustainable Energy & Fuels","volume":null,"pages":null},"PeriodicalIF":5.0000,"publicationDate":"2024-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Flatland materials for photochemical and electrochemical nitrogen fixation applications: from lab-door experiments to large-scale applicability\",\"authors\":\"Syed Asim Ali, Iqra Sadiq and Tokeer Ahmad\",\"doi\":\"10.1039/D4SE00565A\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Rational design of materials in a catalytic system is the main determinant of the efficiency of sustainable energy sources. Significant efforts have focused on the study and development of flatland two-dimensional (2D) materials (MXenes, MBenes, transition metal dichalcogenides/phosphides (TMDs/TMPs), phosphorene, graphene derivatives) towards energy-driven aspirations in consideration of their superior physiochemical properties as compared to their non-layered counterpart materials, surpassing their transport properties and conductivity. Herein, we aim to provide a detailed account of where the flatland materials currently stand to achieve the goal of sustainability in light of their photochemical and electrochemical nitrogen fixation applications. As of now, numerous challenges have limited the expansion of 2D-material derived nitrogen fixation operations for scalable applications. Therefore, we summarized techno-economic analysis and future perspectives of nitrogen fixation applications in relation to their practical ammonia applicability. We have briefly summarized the functionality of flatland materials and classified them on the basis of their photochemical and electrochemical efficiencies.</p>\",\"PeriodicalId\":104,\"journal\":{\"name\":\"Sustainable Energy & Fuels\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.0000,\"publicationDate\":\"2024-06-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sustainable Energy & Fuels\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/se/d4se00565a\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Energy & Fuels","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/se/d4se00565a","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Flatland materials for photochemical and electrochemical nitrogen fixation applications: from lab-door experiments to large-scale applicability
Rational design of materials in a catalytic system is the main determinant of the efficiency of sustainable energy sources. Significant efforts have focused on the study and development of flatland two-dimensional (2D) materials (MXenes, MBenes, transition metal dichalcogenides/phosphides (TMDs/TMPs), phosphorene, graphene derivatives) towards energy-driven aspirations in consideration of their superior physiochemical properties as compared to their non-layered counterpart materials, surpassing their transport properties and conductivity. Herein, we aim to provide a detailed account of where the flatland materials currently stand to achieve the goal of sustainability in light of their photochemical and electrochemical nitrogen fixation applications. As of now, numerous challenges have limited the expansion of 2D-material derived nitrogen fixation operations for scalable applications. Therefore, we summarized techno-economic analysis and future perspectives of nitrogen fixation applications in relation to their practical ammonia applicability. We have briefly summarized the functionality of flatland materials and classified them on the basis of their photochemical and electrochemical efficiencies.
期刊介绍:
Sustainable Energy & Fuels will publish research that contributes to the development of sustainable energy technologies with a particular emphasis on new and next-generation technologies.