美国住宅室内灰尘中液晶单体的浓度、分布和潜在来源。

IF 10.8 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL 环境科学与技术 Pub Date : 2024-07-05 DOI:10.1021/acs.est.4c03131
Yuan Liu, Kurunthachalam Kannan
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引用次数: 0

摘要

液晶单体 (LCM) 是电子数字显示器中使用的以联苯或环己烷为基础的有机化学品,其中有几种具有生物累积性和毒性。人们对它们在美国室内灰尘中的存在情况知之甚少。我们分析了从美国 16 个州收集的 104 个住宅室内灰尘样本中的 60 种 LCM。在灰尘样本中检测到了 60 种 LCM 中的 47 种,∑LCM 浓度中位数为 402 纳克/克(范围:未检测到至 4300 纳克/克)。粉尘样本中经常检测到反式-4-丙基环己基反式、反式-4'-丙基双环己基-4-羧酸酯(MPVBC)和(反式、反式)-4'-氟苯基 4'-戊基-[1,1'-双(环己烷)]-4-羧酸酯(FPeBC)。我们通过测定智能手机屏幕、台式电脑和笔记本电脑显示器以及其他电子设备显示屏中这些化学物质的浓度和特征,调查了灰尘中 LCMs 的潜在来源,发现智能手机中的特征与灰尘中的特征非常吻合。根据计算,美国儿童每天通过摄入灰尘摄入的∑LCM 中位数为 1.19 纳克/千克体重/天,而成人每天通过皮肤吸收摄入的∑LCM 中位数为 0.18 纳克/千克体重/天。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Concentrations, Profiles, and Potential Sources of Liquid Crystal Monomers in Residential Indoor Dust from the United States.

Liquid crystal monomers (LCMs) are biphenyl- or cyclohexane-based organic chemicals used in electronic digital displays, and several of them possess bioaccumulative and toxic properties. Little is known about their occurrence in indoor dust from the United States. We analyzed 60 LCMs in 104 residential indoor dust samples collected from 16 states across the United States. Forty-seven of 60 LCMs were detected in dust samples at a median ∑LCM concentration of 402 ng/g (range: not detected to 4300 ng/g). Trans-4-propylcyclohexyl trans,trans-4'-propylbicyclohexyl-4-carboxylate (MPVBC) and (trans,trans)-4-fluorophenyl 4'-pentyl-[1,1'-bi(cyclohexane)]-4-carboxylate (FPeBC) were frequently detected in dust samples. We investigated potential sources of LCMs in dust by determining concentrations and profiles of these chemicals in smartphone screens, desktop and laptop computer monitors, and displays of other electronic devices and found that profiles in smartphones matched closely with those found in dust. The calculated median daily intake of ∑LCM through dust ingestion was 1.19 ng/kg bw/d for children, whereas that through dermal absorption was 0.18 ng/kg bw/d for adults in the United States.

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来源期刊
环境科学与技术
环境科学与技术 环境科学-工程:环境
CiteScore
17.50
自引率
9.60%
发文量
12359
审稿时长
2.8 months
期刊介绍: Environmental Science & Technology (ES&T) is a co-sponsored academic and technical magazine by the Hubei Provincial Environmental Protection Bureau and the Hubei Provincial Academy of Environmental Sciences. Environmental Science & Technology (ES&T) holds the status of Chinese core journals, scientific papers source journals of China, Chinese Science Citation Database source journals, and Chinese Academic Journal Comprehensive Evaluation Database source journals. This publication focuses on the academic field of environmental protection, featuring articles related to environmental protection and technical advancements.
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