Shangdong Li , Chunmei Zhang , Qiang Gao , Jun Zhao , Xiaowei Cheng , Kaiyuan Mei
{"title":"水泥浆静水压时变规律与早期水化过程之间的关系","authors":"Shangdong Li , Chunmei Zhang , Qiang Gao , Jun Zhao , Xiaowei Cheng , Kaiyuan Mei","doi":"10.1016/j.ngib.2024.05.007","DOIUrl":null,"url":null,"abstract":"<div><p>Annular channeling has seriously troubled deep oil and gas exploitation, and the reduction of hydrostatic pressure of cement slurry in the waiting stage is considered one of the main causes of early annular channeling. However, at present, there is still a lack of sufficient research on and understanding of the relationship between the time-varying law of hydrostatic pressure of cement slurry and the early hydration process in different well sections, especially in high-temperature well sections. Therefore, in this paper, a hydrostatic pressure measurement experiment of cement slurry at low temperature (50–90 °C) and high temperature (120–180 °C) was carried out using a self-developed hydrostatic pressure measurement device of cement slurry. Then, the cement slurry cured at 90 °C for 1–8 h was sampled by the freeze-drying method, and XRD and TG experiments were carried out. The results show that the hydrostatic curves of low and high temperatures both show a trend of rapid increase first, then remain stable, and then decrease rapidly. With an increase in temperature, the time of the stable and falling segments of the hydrostatic curve of the cement slurry gradually decreases. By fitting the rapid pressure drop time points of cement slurry at different temperatures, it can be determined that the rapid pressure drop time and temperature show a functional relationship. The XRD and TG results of different curing times at 90 °C were analyzed. It can be seen that in the early stage of the hydration induction period, the connection between cement particles is not close, and the hydrostatic pressure of the cement slurry column remains stable. As the hydration process enters the acceleration period, the cement particles crosslink with each other through hydration products to form a bridge structure, and the hydrostatic pressure of the cement paste begins to decrease. This shows that the pressure drop time can be controlled by regulating the hydration process to provide theoretical guidance for cement slurry preparation and slurry column design in cementing engineering.</p></div>","PeriodicalId":37116,"journal":{"name":"Natural Gas Industry B","volume":null,"pages":null},"PeriodicalIF":4.2000,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2352854024000408/pdfft?md5=b8b2eb39b2e58fcb6d9666bd5b9f8d63&pid=1-s2.0-S2352854024000408-main.pdf","citationCount":"0","resultStr":"{\"title\":\"The relationship between the time-varying law of the hydrostatic pressureof cement slurry and the early hydration process\",\"authors\":\"Shangdong Li , Chunmei Zhang , Qiang Gao , Jun Zhao , Xiaowei Cheng , Kaiyuan Mei\",\"doi\":\"10.1016/j.ngib.2024.05.007\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Annular channeling has seriously troubled deep oil and gas exploitation, and the reduction of hydrostatic pressure of cement slurry in the waiting stage is considered one of the main causes of early annular channeling. However, at present, there is still a lack of sufficient research on and understanding of the relationship between the time-varying law of hydrostatic pressure of cement slurry and the early hydration process in different well sections, especially in high-temperature well sections. Therefore, in this paper, a hydrostatic pressure measurement experiment of cement slurry at low temperature (50–90 °C) and high temperature (120–180 °C) was carried out using a self-developed hydrostatic pressure measurement device of cement slurry. Then, the cement slurry cured at 90 °C for 1–8 h was sampled by the freeze-drying method, and XRD and TG experiments were carried out. The results show that the hydrostatic curves of low and high temperatures both show a trend of rapid increase first, then remain stable, and then decrease rapidly. With an increase in temperature, the time of the stable and falling segments of the hydrostatic curve of the cement slurry gradually decreases. By fitting the rapid pressure drop time points of cement slurry at different temperatures, it can be determined that the rapid pressure drop time and temperature show a functional relationship. The XRD and TG results of different curing times at 90 °C were analyzed. It can be seen that in the early stage of the hydration induction period, the connection between cement particles is not close, and the hydrostatic pressure of the cement slurry column remains stable. As the hydration process enters the acceleration period, the cement particles crosslink with each other through hydration products to form a bridge structure, and the hydrostatic pressure of the cement paste begins to decrease. This shows that the pressure drop time can be controlled by regulating the hydration process to provide theoretical guidance for cement slurry preparation and slurry column design in cementing engineering.</p></div>\",\"PeriodicalId\":37116,\"journal\":{\"name\":\"Natural Gas Industry B\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2352854024000408/pdfft?md5=b8b2eb39b2e58fcb6d9666bd5b9f8d63&pid=1-s2.0-S2352854024000408-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Natural Gas Industry B\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352854024000408\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Natural Gas Industry B","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352854024000408","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
环状流道严重困扰着深层油气开采,而水泥浆静水压在等待阶段的降低被认为是造成早期环状流道的主要原因之一。然而,目前对不同井段,尤其是高温井段水泥浆静水压时变规律与早期水化过程之间的关系还缺乏足够的研究和认识。因此,本文利用自主研发的水泥浆静水压测量装置,进行了水泥浆在低温(50-90 °C)和高温(120-180 °C)下的静水压测量实验。然后,采用冷冻干燥法对 90 ℃ 固化 1-8 h 的水泥浆进行取样,并进行了 XRD 和 TG 实验。结果表明,低温和高温下的静水压曲线都呈现出先快速上升,然后保持稳定,再快速下降的趋势。随着温度的升高,水泥浆静压曲线稳定段和下降段的时间逐渐缩短。通过拟合不同温度下水泥浆体的快速压力下降时间点,可以确定快速压力下降时间与温度呈函数关系。分析了 90 °C 下不同固化时间的 XRD 和 TG 结果。可以看出,在水化诱导期的初期,水泥颗粒之间的连接并不紧密,水泥浆柱的静水压保持稳定。随着水化过程进入加速期,水泥颗粒之间通过水化产物相互交联形成桥接结构,水泥浆体的静水压力开始下降。这表明可以通过调节水化过程来控制压降时间,为固井工程中的水泥浆制备和浆柱设计提供理论指导。
The relationship between the time-varying law of the hydrostatic pressureof cement slurry and the early hydration process
Annular channeling has seriously troubled deep oil and gas exploitation, and the reduction of hydrostatic pressure of cement slurry in the waiting stage is considered one of the main causes of early annular channeling. However, at present, there is still a lack of sufficient research on and understanding of the relationship between the time-varying law of hydrostatic pressure of cement slurry and the early hydration process in different well sections, especially in high-temperature well sections. Therefore, in this paper, a hydrostatic pressure measurement experiment of cement slurry at low temperature (50–90 °C) and high temperature (120–180 °C) was carried out using a self-developed hydrostatic pressure measurement device of cement slurry. Then, the cement slurry cured at 90 °C for 1–8 h was sampled by the freeze-drying method, and XRD and TG experiments were carried out. The results show that the hydrostatic curves of low and high temperatures both show a trend of rapid increase first, then remain stable, and then decrease rapidly. With an increase in temperature, the time of the stable and falling segments of the hydrostatic curve of the cement slurry gradually decreases. By fitting the rapid pressure drop time points of cement slurry at different temperatures, it can be determined that the rapid pressure drop time and temperature show a functional relationship. The XRD and TG results of different curing times at 90 °C were analyzed. It can be seen that in the early stage of the hydration induction period, the connection between cement particles is not close, and the hydrostatic pressure of the cement slurry column remains stable. As the hydration process enters the acceleration period, the cement particles crosslink with each other through hydration products to form a bridge structure, and the hydrostatic pressure of the cement paste begins to decrease. This shows that the pressure drop time can be controlled by regulating the hydration process to provide theoretical guidance for cement slurry preparation and slurry column design in cementing engineering.