含有和不含 Joncryl® 相容剂的回收聚对苯二甲酸乙二酯/聚酰胺 11 混合物的兼容性和混溶性:机械、热和热机械特性的综合研究

IF 2.4 3区 化学 Q3 POLYMER SCIENCE Iranian Polymer Journal Pub Date : 2024-07-04 DOI:10.1007/s13726-024-01357-y
Unsia Habib, Zahid Iqbal Khan, Zurina Binti Mohamad
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引用次数: 0

摘要

这项创新性研究探讨了再生聚对苯二甲酸乙二酯和聚酰胺 11 (RPET/PA-11) 的兼容性和混溶性,尤其是在使用相容剂 Joncryl® 进行改性后。这项研究是对混合物的详细热性能和热机械性能的首次尝试。值得注意的是,在 RPET 中添加 20% 的 PA-11(按重量计)可显著提高拉伸强度,从 18.5 ± 2.64 兆帕提高到 32.20 ± 4.95 兆帕,弯曲强度从 27.90 ± 3.17 兆帕提高到 46.75 ± 0.78 兆帕,冲击强度从 110.53 焦耳/米提高到 147.12 焦耳/米。此外,加入 2 phr Joncryl® 后,这些强度分别进一步提高到 46.24 ± 0.87 MPa、63.12 ± 4.75 MPa 和 667.68 ± 130.74 J/m。研究表明,添加 20% 的 PA-11 后,RPET 的储存模量从 1128 兆帕增加到 1298.5 兆帕。通过傅立叶变换红外光谱(FTIR)、动态机械分析(DMA)、差示扫描量热仪(DSC)、热重分析(TGA)和扫描电子显微镜(SEM)对相容性和混溶性进行评估,验证了混合物的均匀性。DSC 显示,不同 PA-11 浓度的 RPET/PA-11 混合物的熔化温度与纯 RPET 的熔化温度非常接近,这表明混合物具有稳定的热特性。DSC 结果证实,随着 Joncryl® 含量的增加,冷结晶的 Tm1 温度降低,这表明 RPET 和 PA-11 之间的相互作用和混溶性得到改善。TGA 结果表明,Joncryl® 相容剂(尤其是 2 phr)可通过改善混溶性来提高 RPET/PA-11 混合物的热稳定性。经鉴定,2 phr Joncryl® 混合物的性能最为稳定。这项突破性研究凸显了 RPET 在汽车领域的潜力以及聚合物科学的未来发展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Compatibility and miscibility of recycled polyethylene terephthalate/polyamide 11 blends with and without Joncryl® compatibilizer: a comprehensive study of mechanical, thermal, and thermomechanical properties

This innovative study explores the enhanced compatibility and miscibility of recycled polyethylene terephthalate and polyamide 11 (RPET/PA-11), particularly when modified with Joncryl®, a compatibilizer. This investigation marks the first venture into the detailed thermal and thermo-mechanical properties of the blends. Remarkably, the addition of 20% (by weight) PA-11 to RPET significantly boosts tensile strength from 18.5 ± 2.64 to 32.20 ± 4.95 MPa, flexural strength from 27.90 ± 3.17 to 46.75 ± 0.78 MPa, and impact strength from 110.53 to 147.12 J/m. Furthermore, introducing 2 phr Joncryl® further fortifies these strengths to 46.24 ± 0.87 MPa, 63.12 ± 4.75 MPa, and 667.68 ± 130.74 J/m, respectively. The study revealed a rise in the storage modulus of RPET from 1128 to 1298.5 MPa with 20% (by weight) of PA-11. Compatibility and miscibility assessments through Fourier transformation infrared (FTIR), dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM) validate the blend's uniformity. DSC reveals that the melting temperatures for RPET/PA-11 blends with varying PA-11 concentrations closely match the melting temperature of pure RPET, signifying stable thermal properties. DSC results confirmed that the Tm1 temperature for cold crystallization drops with the addition of Joncryl® content, suggesting improved interaction and miscibility between RPET and PA-11. TGA results disclosed that Joncryl® compatibilizer, especially at 2 phr, boosts the thermal stability of RPET/PA-11 blends by improving miscibility. The 2 phr Joncryl® blend was identified as the most robust in properties. This ground-breaking research highlights the potential of RPET in automotive and future advancements in polymer science.

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来源期刊
Iranian Polymer Journal
Iranian Polymer Journal 化学-高分子科学
CiteScore
4.90
自引率
9.70%
发文量
107
审稿时长
2.8 months
期刊介绍: Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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