使用具有电动特性的氧化铝和二氧化硅复合纳米材料对建筑材料进行性能修复

IF 2.1 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Open Chemistry Pub Date : 2024-07-08 DOI:10.1515/chem-2024-0052
Dingyu Ni, Shengliang Lu, Feng Cai
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引用次数: 0

摘要

近年来,建筑材料的使用寿命已成为人们关注的焦点。其中,混凝土和钢筋的使用寿命尤其受到环境中外部离子(如 Cl-)腐蚀的影响。为了解决这一问题,一种新型的复合纳米胶体通过可控的制备方法被制备出来。该复合纳米胶体以氯化铝溶胶和二氧化硅溶胶为原料制备而成。所制备的胶体粒子粒径分布在 10.5 至 17.5 nm 之间,具有良好的稳定性和分散性。为了验证复合纳米胶体对建筑材料性能的改善作用,实验研究了它对混凝土孔隙率和钢筋防腐性能的影响。结果表明,用复合纳米胶体处理过的混凝土吸湿除湿速度较慢,孔径分布主要集中在 100-1000 nm,说明胶体能有效优化混凝土的孔隙结构。此外,处理后的钢板样品在电化学测试中显示出较高的交流阻抗值和较低的腐蚀电流对数值,表明复合纳米胶体对钢筋腐蚀具有显著的保护作用,可有效改善建筑材料的性能,延长其使用寿命。
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Performance repair of building materials using alumina and silica composite nanomaterials with electrodynamic properties
In recent years, the service life of building materials has become the focus of attention. Among them, the service life of concrete and steel bars is particularly affected by the corrosion of external ions (such as Cl) in the environment. To solve this problem, a new type of composite nanocolloid was prepared through a controllable preparation method. The composite nanocolloid is prepared from aluminum chloride sol and silica sol as raw materials. The prepared colloidal particles have a particle size distribution between 10.5 and 17.5 nm, exhibiting excellent stability and dispersibility. In order to verify the improvement effect of the composite nanocolloid on the properties of building materials, the influence of it on the porosity of concrete and the anti-corrosion performance of steel bars was experimentally studied. The results indicate that the moisture absorption and dehumidification speed of concrete treated with composite nano colloids is slower, and the pore size distribution is mainly concentrated in 100–1,000 nm, indicating that the colloids can effectively optimize the pore structure of concrete. In addition, the processed steel plate samples showed high AC impedance values and low corrosion current logarithmic values in electrochemical testing, indicating that composite nanocolloids have a significant protective effect on the corrosion of steel bars, which can effectively improve the performance of building materials and extend their service life.
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来源期刊
Open Chemistry
Open Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
3.80
自引率
4.30%
发文量
90
审稿时长
6 weeks
期刊介绍: Open Chemistry is a peer-reviewed, open access journal that publishes original research, reviews and short communications in the fields of chemistry in an ongoing way. The central goal is to provide a hub for researchers working across all subjects to present their discoveries, and to be a forum for the discussion of the important issues in the field. The journal is the premier source for cutting edge research in fundamental chemistry and it provides high quality peer review services for its authors across the world. Moreover, it allows for libraries everywhere to avoid subscribing to multiple local publications, and to receive instead all the necessary chemistry research from a single source available to the entire scientific community.
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