聚丙烯比例对聚对苯二甲酸丁二醇酯/聚丙烯混合物形态和机械性能的影响

IF 1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series A Pub Date : 2024-07-10 DOI:10.1134/S0965545X2460042X
Pham Thi Hong Nga,  Nguyen Thanh Tan
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引用次数: 0

摘要

摘要 聚对苯二甲酸丁二醇酯(PBT)具有很强的耐磨性、抗变形性和耐化学性。然而,如何进一步提高 PBT 的冲击韧性仍是许多研究人员关注的问题。本研究旨在通过将 PBT 与聚丙烯(PP)混合来提高其机械性能。拉伸强度、冲击强度、弯曲强度和微观结构均符合 ASTM D638、ASTM D256 和 ASTM D790 标准。在本分析中,PP 与 PBT 按 95/5、90/10、85/15、80/20 和 75/25 的不同比例混合。使用注塑成型技术成型试样进行机械测试。结果显示,冲击强度分别为 3.7、6.6、5.63、5.2、5.1 和 4.9 kJ/m2,分别对应 0、5、10、15、20 和 25% 的 PP。PBT/PP 共混物的冲击强度高于纯 PBT。特别是在 5% PP 样品中,与纯 PBT 相比,冲击强度的提高幅度最大,达到 80.3%。随着 PP 含量的增加,抗弯强度呈下降趋势。经测量,PP 含量分别为 0、5、10、15、20 和 25%时,抗弯强度分别为 77.9、65.6、62.2、58.4、58.2 和 54.0 MPa。混合物的微观结构显示,球形 PP 颗粒与 PBT 基材交织在一起,但未观察到相间粘附。总的来说,选择合适的 PBT/PP 共混物可以在保持拉伸强度的同时提高冲击强度,使其得到广泛应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Effect of Polypropylene Percentage on Morphological and Mechanical Properties of Polybutylene Terephthalate/Polypropylene Blends

Polybutylene terephthalate (PBT) has a strong resistance to abrasion, deformation, and chemical resistance. However, how to further improve the impact toughness of PBT is still an issue that receives the attention of many researchers. This investigation aims to enhance its mechanical properties by mixing it with polypropylene (PP). The tensile strength, impact strength, flexural strength, and microstructure are accorded to ASTM D638, ASTM D256, and ASTM D790. In this analysis, PP was mixed with PBT with different ratios of 95/5, 90/10, 85/15, 80/20, and 75/25. Use injection molding technique to mold specimens for mechanical testing. The results show that the impact strength is 3.7, 6.6, 5.63, 5.2, 5.1, and 4.9 kJ/m2, corresponding to 0, 5, 10, 15, 20, and 25% PP. The impact strength of PBT/PP blends is higher than neat PBT. Especially in the 5% PP sample, the impact strength increase can reach the highest level of 80.3% compared to neat PBT. The flexural strength tends to decrease with increasing PP content. After measuring, we get 77.9, 65.6, 62.2, 58.4, 58.2, and 54.0 MPa, corresponding to 0, 5, 10, 15, 20, and 25% PP. The microstructure of the blends showed that spherical PP particles were interwoven into the PBT substrate, but no interphase adhesion was observed. In general, selecting a suitable PBT/PP blend could improve the impact strength while preserving the tensile strength, allowing it to be applied widely.

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来源期刊
Polymer Science, Series A
Polymer Science, Series A 化学-高分子科学
CiteScore
1.70
自引率
0.00%
发文量
55
审稿时长
3 months
期刊介绍: Polymer Science, Series A is a journal published in collaboration with the Russian Academy of Sciences. Series A includes experimental and theoretical papers and reviews devoted to physicochemical studies of the structure and properties of polymers (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed. Online submission via Internet to the Series A, B, and C is available at http://polymsci.ru.
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