用于吸附和光催化降解微污染物的聚吡咯-Fe2TiO5 复合材料

IF 4.2 2区 工程技术 Q2 ENGINEERING, CHEMICAL Advanced Powder Technology Pub Date : 2024-07-13 DOI:10.1016/j.apt.2024.104565
Agnieszka Sulowska , Agnieszka Fiszka Borzyszkowska , Marcin Pisarek , Konrad Trzciński , Anna Zielińska-Jurek
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引用次数: 0

摘要

本文以硫酸和过氧化氢为氧化剂,采用简易聚合法制备了一系列新的 Fe2TiO5 - 聚吡咯(FTO-xP)。通过漫反射光谱(DR/UV-vis)、傅立叶变换红外光谱(FTIR)、X 射线衍射(XRD)、显微分析(SEM)和比表面积分析(BET)对合成化合物进行了表征,以评估其光学和表面特性、形态、相组成和结晶度。新型复合材料被用于光催化去除微污染物:剧毒六价铬和布洛芬(IBU)。研究了复合材料中聚吡咯含量对所选微量污染物降解效率的影响。结果表明,与单一成分相比,FTO-xP 复合材料具有更好的吸附能力和光催化活性。FTO-xP 混合复合材料可有效去除水相中的无机/有机微污染物。
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Polypyrrole-Fe2TiO5 composites for adsorption and photocatalytic degradation of micropollutants

In this paper, a new series of Fe2TiO5 - polypyrrole (FTO-xP) were prepared by the facile polymerisation method using sulphuric acid and hydrogen peroxide as oxidising agents. The synthesised compounds were characterised by diffuse reflectance spectroscopy (DR/UV–vis), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), microscopic analysis (SEM) and specific surface area analysis (BET) to evaluate their optical and surface properties, morphology, phase composition and crystallinity. The new composites were used for photocatalytic removal of micropollutants: highly toxic Cr(VI) and ibuprofen (IBU). The effect of polypyrrole content in the composite on the efficiency of selected micropollutants degradation was investigated. The results showed that FTO-xP composites had better adsorption capacity and photocatalytic activity than single components. Hybrid FTO-xP composites could efficiently remove inorganic/organic micropollutants in the aqueous phase.

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来源期刊
Advanced Powder Technology
Advanced Powder Technology 工程技术-工程:化工
CiteScore
9.50
自引率
7.70%
发文量
424
审稿时长
55 days
期刊介绍: The aim of Advanced Powder Technology is to meet the demand for an international journal that integrates all aspects of science and technology research on powder and particulate materials. The journal fulfills this purpose by publishing original research papers, rapid communications, reviews, and translated articles by prominent researchers worldwide. The editorial work of Advanced Powder Technology, which was founded as the International Journal of the Society of Powder Technology, Japan, is now shared by distinguished board members, who operate in a unique framework designed to respond to the increasing global demand for articles on not only powder and particles, but also on various materials produced from them. Advanced Powder Technology covers various areas, but a discussion of powder and particles is required in articles. Topics include: Production of powder and particulate materials in gases and liquids(nanoparticles, fine ceramics, pharmaceuticals, novel functional materials, etc.); Aerosol and colloidal processing; Powder and particle characterization; Dynamics and phenomena; Calculation and simulation (CFD, DEM, Monte Carlo method, population balance, etc.); Measurement and control of powder processes; Particle modification; Comminution; Powder handling and operations (storage, transport, granulation, separation, fluidization, etc.)
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