{"title":"离子液体在 Heck 和 Suzuki 反应中作为溶剂和催化剂的作用:全面回顾","authors":"Ravi Tomar, Prapti kundra, Juhi Sharma, Sangeeta","doi":"10.1007/s10563-024-09430-5","DOIUrl":null,"url":null,"abstract":"<p>Ionic liquids (ILs) have overcome solutions to problems associated with increased production with sustainable green approaches over the last three decades. Ionic liquids have appeared as a significant alternative to traditional organic solvents in metal-catalyzed reactions in organic synthesis. This substitution has proven to be instrumental in promoting sustainable development goals by facilitating an eco-friendlier approach to chemical synthesis. Carbon- carbon (C–C) cross-coupling reactions have a decisive role in organic and inorganic chemistry, acting as a flexible tool for the synthesis of complex molecules and materials. These reactions find their applications in various fields, including natural products, pharmaceuticals, and polymers. Among the most frequently used methods for C–C bond formation are the Heck and Suzuki reactions. In this review, we have examined and discussed the recent advancements in the use of ILs as solvents and catalysts in Heck and Suzuki reactions. We have explored various factors such as conversion, yield, catalyst recovery, and time reaction in the context of these reactions over the past few decades. The advantages and accomplishments of using ionic liquids have been evaluated with respect to their potential for enhancing the efficiency of industrial processes.</p>","PeriodicalId":509,"journal":{"name":"Catalysis Surveys from Asia","volume":null,"pages":null},"PeriodicalIF":2.1000,"publicationDate":"2024-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Role of Ionic Liquids as Solvent & Catalyst for Heck and Suzuki Reactions: A Comprehensive Review\",\"authors\":\"Ravi Tomar, Prapti kundra, Juhi Sharma, Sangeeta\",\"doi\":\"10.1007/s10563-024-09430-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Ionic liquids (ILs) have overcome solutions to problems associated with increased production with sustainable green approaches over the last three decades. Ionic liquids have appeared as a significant alternative to traditional organic solvents in metal-catalyzed reactions in organic synthesis. This substitution has proven to be instrumental in promoting sustainable development goals by facilitating an eco-friendlier approach to chemical synthesis. Carbon- carbon (C–C) cross-coupling reactions have a decisive role in organic and inorganic chemistry, acting as a flexible tool for the synthesis of complex molecules and materials. These reactions find their applications in various fields, including natural products, pharmaceuticals, and polymers. Among the most frequently used methods for C–C bond formation are the Heck and Suzuki reactions. In this review, we have examined and discussed the recent advancements in the use of ILs as solvents and catalysts in Heck and Suzuki reactions. We have explored various factors such as conversion, yield, catalyst recovery, and time reaction in the context of these reactions over the past few decades. The advantages and accomplishments of using ionic liquids have been evaluated with respect to their potential for enhancing the efficiency of industrial processes.</p>\",\"PeriodicalId\":509,\"journal\":{\"name\":\"Catalysis Surveys from Asia\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-07-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Surveys from Asia\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10563-024-09430-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Surveys from Asia","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10563-024-09430-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Role of Ionic Liquids as Solvent & Catalyst for Heck and Suzuki Reactions: A Comprehensive Review
Ionic liquids (ILs) have overcome solutions to problems associated with increased production with sustainable green approaches over the last three decades. Ionic liquids have appeared as a significant alternative to traditional organic solvents in metal-catalyzed reactions in organic synthesis. This substitution has proven to be instrumental in promoting sustainable development goals by facilitating an eco-friendlier approach to chemical synthesis. Carbon- carbon (C–C) cross-coupling reactions have a decisive role in organic and inorganic chemistry, acting as a flexible tool for the synthesis of complex molecules and materials. These reactions find their applications in various fields, including natural products, pharmaceuticals, and polymers. Among the most frequently used methods for C–C bond formation are the Heck and Suzuki reactions. In this review, we have examined and discussed the recent advancements in the use of ILs as solvents and catalysts in Heck and Suzuki reactions. We have explored various factors such as conversion, yield, catalyst recovery, and time reaction in the context of these reactions over the past few decades. The advantages and accomplishments of using ionic liquids have been evaluated with respect to their potential for enhancing the efficiency of industrial processes.
期刊介绍:
Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.