离子液体在 Heck 和 Suzuki 反应中作为溶剂和催化剂的作用:全面回顾

IF 2.1 4区 化学 Q3 CHEMISTRY, PHYSICAL Catalysis Surveys from Asia Pub Date : 2024-07-13 DOI:10.1007/s10563-024-09430-5
Ravi Tomar, Prapti kundra, Juhi Sharma,  Sangeeta
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引用次数: 0

摘要

过去三十年来,离子液体(ILs)以可持续的绿色方法解决了与生产增长相关的问题。在有机合成的金属催化反应中,离子液体已成为传统有机溶剂的重要替代品。事实证明,这种替代有助于促进可持续发展目标的实现,因为它有助于采用更环保的方法进行化学合成。碳-碳(C-C)交叉偶联反应在有机和无机化学中起着决定性作用,是合成复杂分子和材料的灵活工具。这些反应可应用于天然产物、药物和聚合物等多个领域。最常用的 C-C 键形成方法是 Heck 反应和铃木反应。在本综述中,我们研究并讨论了在 Heck 和 Suzuki 反应中使用 IL 作为溶剂和催化剂的最新进展。在过去几十年中,我们探讨了这些反应中的转化率、产率、催化剂回收率和反应时间等各种因素。我们评估了使用离子液体在提高工业流程效率方面的优势和成就。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Role of Ionic Liquids as Solvent & Catalyst for Heck and Suzuki Reactions: A Comprehensive Review

Ionic liquids (ILs) have overcome solutions to problems associated with increased production with sustainable green approaches over the last three decades. Ionic liquids have appeared as a significant alternative to traditional organic solvents in metal-catalyzed reactions in organic synthesis. This substitution has proven to be instrumental in promoting sustainable development goals by facilitating an eco-friendlier approach to chemical synthesis. Carbon- carbon (C–C) cross-coupling reactions have a decisive role in organic and inorganic chemistry, acting as a flexible tool for the synthesis of complex molecules and materials. These reactions find their applications in various fields, including natural products, pharmaceuticals, and polymers. Among the most frequently used methods for C–C bond formation are the Heck and Suzuki reactions. In this review, we have examined and discussed the recent advancements in the use of ILs as solvents and catalysts in Heck and Suzuki reactions. We have explored various factors such as conversion, yield, catalyst recovery, and time reaction in the context of these reactions over the past few decades. The advantages and accomplishments of using ionic liquids have been evaluated with respect to their potential for enhancing the efficiency of industrial processes.

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来源期刊
Catalysis Surveys from Asia
Catalysis Surveys from Asia 化学-物理化学
CiteScore
4.80
自引率
0.00%
发文量
29
审稿时长
>12 weeks
期刊介绍: Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.
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