{"title":"带有聚苯乙烯磺酸盐颗粒和交联聚乙烯醇中的聚乙烯亚胺的电荷图案纳滤膜","authors":"Ali Behboudi , Philipp Jahn , Mathias Ulbricht","doi":"10.1016/j.memlet.2024.100078","DOIUrl":null,"url":null,"abstract":"<div><p>Removing salinity has always been a challenge for wastewater treatment. Utilizing nanofiltration (NF) membranes is a promising approach. However, currently available NF membranes are less effective in monovalent salt removal. In this study, work toward the initial aim of fabricating charge mosaic membranes led to charge-patterned NF-selective films on polyether sulfone (PES) or polyacrylonitrile (PAN) support membranes, with similar rejection for mono- and divalent salts. The membranes were fabricated by a two-step layer assembly of first negatively charged polystyrene sulfonate (PSS) particles immobilized in a polyvinyl alcohol (PVA) layer, followed by coating a positively charged polyethyleneimine (PEI) layer. Both PVA and PEI were crosslinked using glutaraldehyde that had initially been impregnated into the support membrane. The type of support membrane, nanoparticle, PVA, and PEI concentrations during fabrication, as well as feed pH and salt concentration, play significant roles in separation performance of obtained composite membranes. Charge-patterned NF membranes fabricated using 0.5 wt.% PVA and 0.05 wt.% PSS for assembly of the first layer followed by coating 0.5 wt.% PEI solution had even somewhat higher rejection for monovalent salt (NaCl; ∼82%) compared to multivalent salts (Na<sub>2</sub>SO<sub>4</sub>, MgSO<sub>4</sub>, and MgCl<sub>2</sub>; ∼74%), at a permeance of 5.5 LMH/bar on the PES and 3.1 LMH/bar on the PAN support membrane.</p></div>","PeriodicalId":100805,"journal":{"name":"Journal of Membrane Science Letters","volume":"4 2","pages":"Article 100078"},"PeriodicalIF":4.9000,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772421224000126/pdfft?md5=fe4f38456e65fab7493e29dffa1f4c18&pid=1-s2.0-S2772421224000126-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Charge-patterned nanofiltration membranes with polystyrene sulfonate particles and polyethyleneimine in cross-linked polyvinyl alcohol\",\"authors\":\"Ali Behboudi , Philipp Jahn , Mathias Ulbricht\",\"doi\":\"10.1016/j.memlet.2024.100078\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Removing salinity has always been a challenge for wastewater treatment. Utilizing nanofiltration (NF) membranes is a promising approach. However, currently available NF membranes are less effective in monovalent salt removal. In this study, work toward the initial aim of fabricating charge mosaic membranes led to charge-patterned NF-selective films on polyether sulfone (PES) or polyacrylonitrile (PAN) support membranes, with similar rejection for mono- and divalent salts. The membranes were fabricated by a two-step layer assembly of first negatively charged polystyrene sulfonate (PSS) particles immobilized in a polyvinyl alcohol (PVA) layer, followed by coating a positively charged polyethyleneimine (PEI) layer. Both PVA and PEI were crosslinked using glutaraldehyde that had initially been impregnated into the support membrane. The type of support membrane, nanoparticle, PVA, and PEI concentrations during fabrication, as well as feed pH and salt concentration, play significant roles in separation performance of obtained composite membranes. Charge-patterned NF membranes fabricated using 0.5 wt.% PVA and 0.05 wt.% PSS for assembly of the first layer followed by coating 0.5 wt.% PEI solution had even somewhat higher rejection for monovalent salt (NaCl; ∼82%) compared to multivalent salts (Na<sub>2</sub>SO<sub>4</sub>, MgSO<sub>4</sub>, and MgCl<sub>2</sub>; ∼74%), at a permeance of 5.5 LMH/bar on the PES and 3.1 LMH/bar on the PAN support membrane.</p></div>\",\"PeriodicalId\":100805,\"journal\":{\"name\":\"Journal of Membrane Science Letters\",\"volume\":\"4 2\",\"pages\":\"Article 100078\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2024-07-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2772421224000126/pdfft?md5=fe4f38456e65fab7493e29dffa1f4c18&pid=1-s2.0-S2772421224000126-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Membrane Science Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2772421224000126\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Membrane Science Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772421224000126","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Charge-patterned nanofiltration membranes with polystyrene sulfonate particles and polyethyleneimine in cross-linked polyvinyl alcohol
Removing salinity has always been a challenge for wastewater treatment. Utilizing nanofiltration (NF) membranes is a promising approach. However, currently available NF membranes are less effective in monovalent salt removal. In this study, work toward the initial aim of fabricating charge mosaic membranes led to charge-patterned NF-selective films on polyether sulfone (PES) or polyacrylonitrile (PAN) support membranes, with similar rejection for mono- and divalent salts. The membranes were fabricated by a two-step layer assembly of first negatively charged polystyrene sulfonate (PSS) particles immobilized in a polyvinyl alcohol (PVA) layer, followed by coating a positively charged polyethyleneimine (PEI) layer. Both PVA and PEI were crosslinked using glutaraldehyde that had initially been impregnated into the support membrane. The type of support membrane, nanoparticle, PVA, and PEI concentrations during fabrication, as well as feed pH and salt concentration, play significant roles in separation performance of obtained composite membranes. Charge-patterned NF membranes fabricated using 0.5 wt.% PVA and 0.05 wt.% PSS for assembly of the first layer followed by coating 0.5 wt.% PEI solution had even somewhat higher rejection for monovalent salt (NaCl; ∼82%) compared to multivalent salts (Na2SO4, MgSO4, and MgCl2; ∼74%), at a permeance of 5.5 LMH/bar on the PES and 3.1 LMH/bar on the PAN support membrane.