纳米-BN 和纳米纤维素协同增强了纤维素绝缘纸的机械、热和绝缘性能

IF 8.3 1区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Composites Science and Technology Pub Date : 2024-07-08 DOI:10.1016/j.compscitech.2024.110748
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引用次数: 0

摘要

高湿、高热、高海拔和复杂电场等复杂苛刻的环境要求对绝缘纸的机械性能、热稳定性和电绝缘性能提出更高的标准。然而,单靠一种纳米材料很难提高整体性能。因此,我们建议采用不同尺寸的两相纳米材料来协同提高纤维素绝缘纸的性能。因此,我们采用 "模拟设计直接指导实验研究 "的方法,通过分子动力学模拟构建了纳米 BN/纳米纤维素/纤维素(nano-BN/NFC/cellulose)模型,并对其力学参数、介电性能、热稳定性等进行了模拟和计算。根据模拟结果,制备出了合适比例的纳米-BN/NFC/纤维素绝缘纸。纳米 BN 和 NFC 协同增强了绝缘纸的机械性能。在重力作用下,纳米-BN、CNF 和纤维素逐层排列,使填料沿平面对角重叠,协同形成有利于热传递的导热网络。此外,三相材料之间形成了强烈的界面效应,降低了整体结构的极化效应和电荷积累,协同提高了电气绝缘性能。12%nano-BN/NFC/cellulose (P12) 具有最佳的整体性能,有望用于在高湿度和高热量的特殊环境中运行的电力设备。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Nano-BN and nano-cellulose synergistically enhanced the mechanical, thermal, and insulating properties of cellulose insulating paper

The complex and demanding environments of high humidity, heat, altitude, and intricate electric fields necessitate higher standards for the mechanical, thermal stability, and electric insulation properties of insulating paper. However, a single nanomaterial alone struggles to enhance overall performance. Hence, we propose employing two-phase nanomaterials with distinct dimensions to synergistically enhance the performance of cellulose insulation paper. Accordingly, “simulation design directly guided experimental research” was utilized in constructing nano-BN/nanocellulose/cellulose (nano-BN/NFC/cellulose) models through molecular dynamics simulation, and its mechanical parameters, dielectric properties, thermal stability, and so on were simulated and calculated. Based on simulation results, suitable proportions of nano-BN/NFC/cellulose insulating paper were prepared. Nano-BN and NFC synergistically enhance the mechanical properties of insulating paper. The nano-BN, CNF, and cellulose are arranged layer by layer under the action of gravity, allowing the fillers to overlap diagonally along the plane, synergistically forming a thermally conductive network conducive to heat transfer. Additionally, a strong interfacial effect is formed between the three-phase materials, reducing the overall structure's polarization effect and charge accumulation, and synergistically enhancing electrical insulation performance. The 12%nano-BN/NFC/cellulose (P12) exhibits optimal overall performance and is expected to be used in power equipment operating in special environments with high humidity and heat.

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来源期刊
Composites Science and Technology
Composites Science and Technology 工程技术-材料科学:复合
CiteScore
16.20
自引率
9.90%
发文量
611
审稿时长
33 days
期刊介绍: Composites Science and Technology publishes refereed original articles on the fundamental and applied science of engineering composites. The focus of this journal is on polymeric matrix composites with reinforcements/fillers ranging from nano- to macro-scale. CSTE encourages manuscripts reporting unique, innovative contributions to the physics, chemistry, materials science and applied mechanics aspects of advanced composites. Besides traditional fiber reinforced composites, novel composites with significant potential for engineering applications are encouraged.
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