碱性介质中的溶解铁:了解其对分水反应影响的技术和见解

IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL Current Opinion in Electrochemistry Pub Date : 2024-06-29 DOI:10.1016/j.coelec.2024.101568
Arthur Bukowski , Pierre-Yves Olu , Armand Gering , Marian Chatenet , Antoine Bonnefont
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引用次数: 0

摘要

碱性介质中的溶解铁是影响一系列电化学反应的重要课题,尤其是发生在碱性水电解槽中的反应。本研究汇编了过去几年中用于帮助解决这一挑战性问题的研究技术和策略。重点讨论了铁在所研究介质中的溶解度、使用优质参比电解质的重要性、在何处以及如何测量系统中的铁含量,还讨论了关于溶解铁对氢进化反应和氧进化反应的影响的共识和争论,特别是这些电解质杂质增强或改变反应动力学的方式。
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Dissolved iron in alkaline media: Techniques and insights for understanding its effects on water-splitting reactions

Dissolved iron in alkaline media is an important topic influencing a wide array of electrochemical reactions and most notably those occurring in alkaline water electrolysers. This work compiles the study techniques and strategies that have been used in the past few years to help tackle this challenging issue. Focus is made on iron solubility in the studied medias, the importance of using a quality reference electrolyte, where and how to measure iron content in the system, and also on what is agreed and what is debated concerning the influence of dissolved iron on the hydrogen evolution reaction and oxygen evolution reaction, notably in the way these electrolyte impurities do enhance or alter the reactions kinetics.

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来源期刊
Current Opinion in Electrochemistry
Current Opinion in Electrochemistry Chemistry-Analytical Chemistry
CiteScore
14.00
自引率
5.90%
发文量
272
审稿时长
73 days
期刊介绍: The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner: 1.The views of experts on current advances in electrochemistry in a clear and readable form. 2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications. In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle: • Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •
期刊最新文献
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