带有活性剂发泡的热塑性聚氨酯的压缩行为,用于 3D 打印定制舒适鞋垫

IF 5 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Polymer Testing Pub Date : 2024-07-14 DOI:10.1016/j.polymertesting.2024.108517
Mariana Cristiana Iacob , Diana Popescu , Contantin Stochioiu , Florin Baciu , Anton Hadar
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引用次数: 0

摘要

本研究的主要目的是研究由热塑性聚氨酯长丝(特别是含有发泡剂的 colorFabb varioShore TPU)制成的三维打印试样的压缩行为。发泡技术可以通过调整影响膨胀程度的工艺参数(如打印温度、打印速度或流动比率)来操纵三维打印的特性。这一功能为三维打印个性化足部矫形器或以静态舒适为导向的应用提供了新的可能性,可根据应用要求定制打印刚度。由于填充密度和填充图案也会影响三维打印的抗压特性,因此本研究将这两个参数与打印温度一起作为自变量加以考虑。因此,在压缩测试中对打印温度设定为 190 ℃、220 ℃ 和 240 ℃的试样、陀螺型和蜂窝型试样以及填充密度从 10 % 到 35 %(以 5 % 为增量)的试样进行了实验研究。评估的目的是根据既定标准,确定这些因素在 10 % 和 20 % 应变时对印花刚度的影响。研究结果具有重要的实用价值,因为它们提供了数据,以便在开发量身定制的足部矫形器(鞋垫)时,根据足底压力峰值测量数据调整可变刚度,而这正是研究的第二个目标。影响压缩强度的最大因素是印刷温度,其次是填充密度和图案类型。10 % 和 20 % 应变之间的压缩模量差异不具有统计学意义。此外,主效应图显示,在 220 ℃ 和 240 ℃ 时,压缩模量效应的变化极小,而在 190 ℃ 印刷温度时,压缩模量效应的差异很大,扫描电子显微镜的研究也证实了这一点,在 220 ℃ 时显示的是发泡层,而在 190 ℃ 时显示的是未发泡层。此外,交互图显示所研究的变量之间没有明显的交互效应。此外,对测试前和测试后两个月的样品尺寸和密度进行比较后发现,样品没有发生明显的变化。 在应用于定制矫形鞋时(定制了五双鞋垫并进行了测试),实验结果表明,根据填充物的不同,足底压力峰值的降低和分布也有所不同。
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Compressive behavior of thermoplastic polyurethane with an active agent foaming for 3D-printed customized comfort insoles

The primary objective of this study was to investigate the compressive behavior of 3D-printed specimens made of a thermoplastic polyurethane filament, specifically colorFabb varioShore TPU, which incorporates a foaming agent. The foaming technology makes it possible to manipulate 3D prints' properties by adjusting process parameters that affect the level of expansion, such as printing temperature, printing speed or flow ratio. This capability opens new possibilities for 3D-printed personalized foot orthotics or for static comfort-oriented applications by tailoring the stiffness of the print based on the application requirements. Since infill density and infill pattern also affect the compressive characteristics of 3D prints, this research took these two parameters into account as independent variables, alongside the printing temperature. Thus, the specimens with printing temperatures set at 190 °C, 220 °C, and 240 °C, gyroid and honeycomb patterns, and infill variations from 10 % to 35 % in 5 % increments were experimentally investigated in compression testing. The evaluation was conducted to determine the influence of these factors on the stiffness of prints at 10 % and 20 % strains, in accordance with established standard. The findings had an important practical value as they provide data for adjusting the variable stiffness based on peak plantar pressure measurement data when developing tailored foot orthoses (insoles), which was the second objective of the research. The most influential factor affecting the compressive strength was the printing temperature, followed by infill density and pattern type. The difference in compression modulus between 10 % and 20 % strains did not exhibit statistical significance. Moreover, the main effects plots indicated minimal variations in compression modulus effects at 220 °C and 240 °C, whereas an important difference was observed at 190 °C printing temperature, which was confirmed by scanning electron microscopy investigations showing foamed layers at 220 °C and unfoamed layers at 190 °C. Furthermore, interaction plots revealed no significant interaction effect among the studied variables. Additionally, a comparison of samples’ sizes and densities before and two months after testing indicated no observable modifications When applied to custom orthotics (five pairs of insoles were customized and tested), the experimental findings documented variations in the reduction and distribution of peak plantar pressure based on the infill variability.

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来源期刊
Polymer Testing
Polymer Testing 工程技术-材料科学:表征与测试
CiteScore
10.70
自引率
5.90%
发文量
328
审稿时长
44 days
期刊介绍: Polymer Testing focuses on the testing, analysis and characterization of polymer materials, including both synthetic and natural or biobased polymers. Novel testing methods and the testing of novel polymeric materials in bulk, solution and dispersion is covered. In addition, we welcome the submission of the testing of polymeric materials for a wide range of applications and industrial products as well as nanoscale characterization. The scope includes but is not limited to the following main topics: Novel testing methods and Chemical analysis • mechanical, thermal, electrical, chemical, imaging, spectroscopy, scattering and rheology Physical properties and behaviour of novel polymer systems • nanoscale properties, morphology, transport properties Degradation and recycling of polymeric materials when combined with novel testing or characterization methods • degradation, biodegradation, ageing and fire retardancy Modelling and Simulation work will be only considered when it is linked to new or previously published experimental results.
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