2-amino 5-methyl benzimidazole 与 2-bromo Isophthalaldehyde 衍生的新型希夫碱配体的一些特定过渡金属配合物的绿色高效合成、光谱、表征和抗菌活性

Sadashiv N. Sinkar, Ram. B. Kohire, Dnyaneshwar T. Nagre
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引用次数: 0

摘要

用科学的微波方法绿色高效地合成了由 2-氨基 5-甲基苯并咪唑和 2-溴间苯二甲醛衍生的新型配体。金属络合物由氯化锰(II)和 Co(II)、Ni(II)、Cu(II)、Zn(II)、Cd(II)盐的硝酸盐与新型配体生成。通过 TLC 和每个络合物的熔点可以确认金属络合物的形成。通过元素分析、红外光谱、1HNMR 和质谱对新型配体进行了表征,并通过紫外光谱和红外光谱对金属络合物进行了表征。通过热重分析(TGA)研究了锌(II)和镉(II)配合物的热稳定性。所有金属复合物都对大肠杆菌、金黄色葡萄球菌和伤寒杆菌具有抗菌活性。
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Green and Efficient Synthesis, Spectroscopic, Characterization, Antibacterial Activity of Some Selected Transition Metal Complexes of Novel Schiff Base Ligand Derived from 2-amino 5-methyl benzimidazole with 2-bromo Isophthalaldehyde
A Green and efficient environmentally synthesis using scientific microwave method of novel ligand derived from 2-amino 5-methyl benzimidazole with 2-bromo Isophthalaldehyde. Metal complexes were derived from Mn(II) chloride and nitrate of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), salts with novel ligand at the end of the reaction all metal complexes show fine colour. By TLC and melting point of each complex was confirming the formation of metal complex. Characterization of novel ligand carried out by elemental analysis, IR,1HNMR, Mass spectroscopy and characterization of metal complexes carried out by UV, IR. The thermal stability of Zn (II) and Cd (II) complexes was studied by thermo-gravimetric analyses (TGA). All metal complexes show antibacterial activity against E-Coli, S.Aureus and S.Typhi.
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