传热对超临界二氧化碳萃取工艺的加压、萃取和减压阶段的影响。2.模拟双容器工业装置

IF 3.4 3区 工程技术 Q2 CHEMISTRY, PHYSICAL Journal of Supercritical Fluids Pub Date : 2024-07-10 DOI:10.1016/j.supflu.2024.106348
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引用次数: 0

摘要

在这项工作中,我们模拟了双容器(1 立方米,长径比为 4)工业设备中的传热情况,以评估翻新阶段形成的温度梯度对萃取曲线的影响。我们模拟了在 48 兆帕和 40 °C(外加温度梯度的情况)或 60 °C(调节阶段产生温度梯度的情况)条件下,使用 5 毫米/秒的二氧化碳萃取 1 毫米的颗粒,辅助流体温度为 60 °C。这些非等温萃取的结果与代表性等温萃取的结果进行了比较。温度梯度对非等温情况下的累积萃取曲线有轻微影响。我们考虑了装有固体基质的篮子的存在。我们还将浅层二氧化碳速度改为 3 或 10 毫米/秒,将颗粒大小改为 0.50 或 1.25 毫米,以比较萃取曲线。篮子以及二氧化碳表层速度和颗粒大小的变化影响不大。我们模拟了温度和压力更高的极限情况(80 °C 和 70 MPa),在这种情况下,萃取时间极短(10 分钟),并且在修整阶段形成了更明显的温度梯度。在这种极端萃取条件下,我们观察到的差异比在所需萃取温度下使用等温萃取工艺时更为明显。
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Effect of heat transfer on the pressurization, extraction, and depressurization stages of a supercritical CO2 extraction process. 2. Simulation of a two-vessel industrial plant

In this work, we simulated the heat transfer in a two-vessel (1-m3, length-to-diameter ratio of 4) industrial plant to assess the effect of the temperature gradients formed during the reconditioning stage on the extraction curves. We simulated the extraction of 1-mm particles using 5 mm/s of CO2 at 48 MPa and 40 °C (case with an imposed temperature gradient) or 60 °C (case with temperature gradients from the reconditioning stage), with the service fluid at 60 °C. The results of these non-isothermal extractions were compared with those obtained in representative isothermal cases. The temperature gradients slightly affected the cumulative extraction curves in non-isothermal cases. We considered the presence of a basket containing the solid substrate. We also changed the superficial CO2 velocity to 3 or 10 mm/s and the particle size to 0.50 or 1.25 mm to compare the extraction curves. The effects of the basket and the changes in superficial CO2 velocity and particle size were minor. We simulated a limit case with higher temperature and pressure (80 °C and 70 MPa), where the extraction time was extremely short (10 min) and more significant temperature gradients were formed during the reconditioning stage. We observed more significant differences at this extreme extraction condition than when using an isothermal process at the required extraction temperature.

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来源期刊
Journal of Supercritical Fluids
Journal of Supercritical Fluids 工程技术-工程:化工
CiteScore
7.60
自引率
10.30%
发文量
236
审稿时长
56 days
期刊介绍: The Journal of Supercritical Fluids is an international journal devoted to the fundamental and applied aspects of supercritical fluids and processes. Its aim is to provide a focused platform for academic and industrial researchers to report their findings and to have ready access to the advances in this rapidly growing field. Its coverage is multidisciplinary and includes both basic and applied topics. Thermodynamics and phase equilibria, reaction kinetics and rate processes, thermal and transport properties, and all topics related to processing such as separations (extraction, fractionation, purification, chromatography) nucleation and impregnation are within the scope. Accounts of specific engineering applications such as those encountered in food, fuel, natural products, minerals, pharmaceuticals and polymer industries are included. Topics related to high pressure equipment design, analytical techniques, sensors, and process control methodologies are also within the scope of the journal.
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