通过过渡金属催化 1,3 二烯与二硅烷的硅烷化反应合成烯丙基硅烷的研究进展

IF 18 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-07-01 DOI:10.1093/chemle/upae134

Nobuki Katayama, Yasushi Obora

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引用次数: 0

摘要

本重点综述概述了通过过渡金属催化 1,3 二烯与二硅烷的硅烷化反应合成烯丙基硅烷的研究进展。我们特别回顾了安装 2 个硅原子的二硅烷化法和使用二硅烷及亲核剂和亲电剂等试剂安装硅和另一个原子的硅烷官能化法。利用这些方法对 1,3-二烯进行硅烷化处理，可提供一种稳健的方案，只需一步就能高效合成所需的烯丙基硅烷，从而简化了 1,3-二烯的硅烷官能化过程。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Developments in the synthesis of allylsilanes by transition metal–catalyzed silylation of 1,3-dienes with disilanes

This highlight review overviews developments in the synthesis of allylsilanes by transition metal–catalyzed silylation of 1,3-dienes with disilanes. We specifically review disilylation, which installs 2 silicon atoms, and silyl-functionalization, which installs both silicon and another atom using disilanes and reagents such as nucleophiles and electrophiles. Utilizing these methods for the silylation of 1,3-dienes provides a robust protocol for the efficient synthesis of the desired allylsilanes in 1 step, thereby streamlining the silyl-functionalization of 1,3-dienes.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.