使用桉树叶提取物制备的铁/镍涂层砂纳米复合材料去除水溶液中的铜

Anwar Qasim Saeed, Hebatallah Mohammed Khudhair, Ali Saud Hadi Alhamdani, Shahad L. Abbas, M. Abdulhasan
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摘要

如今,水体中普遍存在重金属,因此,同时去除这些污染物的高效方法变得越来越重要。本研究采用桉树叶萃取物,以环保的方法在沙子上涂覆铁/镍纳米粒子。使用傅立叶变换红外光谱法(FT-IR)分析了铁/镍涂层砂的绿色合成特征。然后,在批量实验中使用得到的铁/镍纳米复合涂层砂去除水中的铜(Cu(II))。研究考察了影响铜(II)去除效率的五个因素,即溶液的 pH 值、铜(II)浓度、接触时间、铁/镍纳米复合材料包覆砂的用量和搅拌速度。这些因素的最佳值为 200 rpm、pH 值 6、130 分钟、Cu(II) 浓度 50 mg/L、0.5 g/50 mL Fe/Ni 涂层砂。研究结果表明,在第五个循环之前,超过 80% 的 Cu(II) 被去除。这项研究为利用废物制成的环保型复合材料处理受铜离子污染的水提供了新的可能性。
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Using Iron/Nickel Coated Sand Nanocomposites Prepared by Eucalyptus Leaf Extract for Copper Removal from Aqueous Solutions
As heavy metals are commonly found in water bodies today, the need for an efficient method to remove these pollutants simultaneously has become increasingly important. This research involved coating sand with Fe/Ni nanoparticles created through an environmentally friendly method using eucalyptus leaf extract. Green synthesis of Fe/Ni coated sand was characterized using Fourier transform-infrared spectrometry (FT-IR) analysis. The resulting Fe/Ni nanocomposite coated sand was then used to copper (Cu(II)) removal from water in batch experiments. The study examined five factors namely pH of solution, Cu(II) concentration, contact time, Fe/Ni coated sand dosage, and agitation speed that affected on the Cu(II) removal efficiency. Optimal values of this factors were found to be 200 rpm, pH 6, 130 minutes, 50 mg/L for Cu(II), and 0.5 g/50 mL Fe/Ni coated sand. The findings revealed that over 80% of Cu(II) was removed until the fifth cycle. This work could open up new possibilities for treating water contaminated with copper ions using eco-friendly composites made from waste.
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